Sur les carbonates basiques de fer (III): I. Carbonate basique de fer (III) amorphe

Abstract

The preparation of a non‐stoichiometric basic carbonate of iron (III) is described. The amounts of carbon dioxide and water can vary in large limits, depending on the way the samples are dried. The ratio of Fe2O3:CO2 in a fresh product is nearly one, but decomposition takes place already at room temperature and ambient humidity. When heated slowly, the carbon dioxide is given of in two clear steps, an intermediate product being formed at about 200°C. The basic iron (III) carbonate decomposes between 400° and 500°C to an α‐Fe2O3 with still a small amount of carbon dioxide. The infrared spectra show that in the freshly prepared products the greater part of the CO 32− ions are linked by two oxygen atoms to two iron atoms, and a smaller part probably only by one oxygen to one iron atom. In the intermediate product, part of the CO2_3 ions are linked by two oxygen atoms to one iron atom, or a hydrogenocarbonate group may be formed. The X‐ray diagrams taken with Mo Kα rays show only two broad lines.