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The sections in this article are Preparation of Au Surfaces and Double‐layer Properties Polycrystalline ( pc ‐ Au ) and Single‐crystal Au / H 2 O Interface pc ‐ Au and Single‐crystal Au /Nonaqueous Solutions Interface Adsorption of Inorganic Compounds on Gold Electrodes Sulfate Hydroxide Nitrate Chloride Bromide Iodide Cyanide Thiocyanate Other Inorganic Species Adsorption of Organic Compounds on Gold Electrodes Adsorption of Sulfur‐containing Compounds Adsorption of Thiols Adsorption of Modified Thiols Adsorption of Thiourea Adsorption of Disulfides and Related Compounds Other Sulfur Compounds and Complex Adsorption Layers Adsorption of Selenium‐containing Compounds Adsorption of Nitrogen‐containing Compounds Pyridine and its Derivatives Pyrazine Amines and Other Nitrogen‐containing Compounds Adsorption of Other Organic Compounds Alcohols Aminoacids Other Organic Acids Nucleic Bases and Other Biochemical Compounds Other Compounds Reconstruction of the Surface of Gold Electrodes Formation of Oxides on Gold Electrodes Underpotential Deposition of Various Metals on Au Cu Cd Pd S , Se , and Te Sulfur Selenium Tellurium Bi Pt Ni Co Sb Sn Al Tl Pb Zn Ge Rh Li Fe Ag Hg Electrochemistry of Coordination Compounds of Gold. Electrodissolution and Electrodeposition of Au Au Electrodeposition Au Electrodissolution Gold Clusters
The sections in this article are Preparation of Au Surfaces and Double‐layer Properties Polycrystalline ( pc ‐ Au ) and Single‐crystal Au / H 2 O Interface pc ‐ Au and Single‐crystal Au /Nonaqueous Solutions Interface Adsorption of Inorganic Compounds on Gold Electrodes Sulfate Hydroxide Nitrate Chloride Bromide Iodide Cyanide Thiocyanate Other Inorganic Species Adsorption of Organic Compounds on Gold Electrodes Adsorption of Sulfur‐containing Compounds Adsorption of Thiols Adsorption of Modified Thiols Adsorption of Thiourea Adsorption of Disulfides and Related Compounds Other Sulfur Compounds and Complex Adsorption Layers Adsorption of Selenium‐containing Compounds Adsorption of Nitrogen‐containing Compounds Pyridine and its Derivatives Pyrazine Amines and Other Nitrogen‐containing Compounds Adsorption of Other Organic Compounds Alcohols Aminoacids Other Organic Acids Nucleic Bases and Other Biochemical Compounds Other Compounds Reconstruction of the Surface of Gold Electrodes Formation of Oxides on Gold Electrodes Underpotential Deposition of Various Metals on Au Cu Cd Pd S , Se , and Te Sulfur Selenium Tellurium Bi Pt Ni Co Sb Sn Al Tl Pb Zn Ge Rh Li Fe Ag Hg Electrochemistry of Coordination Compounds of Gold. Electrodissolution and Electrodeposition of Au Au Electrodeposition Au Electrodissolution Gold Clusters
The sections in this article are Introduction NAD ( P ) + / NAD ( P ) in Living Systems Formal Potential of the NAD + / NADH Redox Couple Focus and Scope of the Chapter Direct Electrochemical Oxidation of NAD ( P ) H General Observations Effect of Adsorption Mechanism and Kinetics Homogeneous Oxidation of NAD ( P ) H by Oxidizing Redox Compounds One‐electron No‐proton Acceptors Two‐electron‐proton Acceptors o ‐quinones and p ‐quinones Aromatic Diimines Electrocatalytic Oxidation of NAD ( P ) H at Mediator‐modified Electrodes General Remarks of CMEs o ‐Quinones and Phenylenediimine Derivatives Other Mediating Functionalities and Metal‐coated Electrodes Catalytic NADH Oxidation at CMEs Based on Polymers Mechanistic and Kinetic Aspects CMEs Based on NADH ‐oxidizing Enzymes Amperometric Biosensors Based on NAD ( P )‐dependent Dehydrogenase Enzymes Direct Electrochemical Reduction of NAD ( P ) + General Observations Adsorption Phenomena Mechanism and Kinetics Electrocatalytic Reduction of NAD ( P ) + Nonenzymatic Electroreduction of NAD ( P ) + Enzymatic Electroreduction of NAD ( P ) + Acknowledgment
In which orientation does adenine adsorb on gold and silver surfaces? This question has been a matter of debate for over 30 years. Since the dawn of surface-enhanced Raman spectroscopy (SERS); it and other techniques such as tip-enhanced Raman spectroscopy (TERS), surface-enhanced infrared absorption spectroscopy (SEIRAS), scanning tunneling microscopy (STM), density functional theory (DFT) simulations, and more, have been used in many attempts to answer this seemingly straightforward, yet controversial, question. Herein, the timeline and recent advances on this topic are explored, and the frequently contradictory findings are put into context and discussed.
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