Silicon and fluorine co-doped anatase TiO 2 (Si-F-TiO 2 ) photocatalysts with enhanced photocatalytic activity were successfully prepared via a facile two-step synthetic method by using SiO 2 powders and (NH 4 ) 2 TiF 6 as the precursors. The obtained products were thoroughly characterized by various techniques, including scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscope (XPS), UV-visible diffuse reflectance spectroscopy and N 2 adsorption-desorption analysis. These characterizations reveal the effects of molar ratio of silica to titanium(R) and pH value on morphology, size and crystal structure of Si-F-TiO 2 samples. We find that the band gap of the catalyst can be engineered from 3.16 to 2.88 eV via altering the molar ratio of Si : Ti and pH value.Compared with un-doped or F-doped TiO 2 , co-doped Si-F-TiO 2 samples exhibited improved photocatalytic degradation toward different dye molecules under both ultraviolet and visible light illumination. With the aid of holes and radicals trapping experiments, we proposed the photocatalytic mechanism for the examined systems. Furthermore, first-principle calculations provide theoretic insights for the enhanced photocatalytic performance of codoped Si-F-TiO 2 photocatalyst.