Diamond films were grown on silicon by microwave chemical-vapor deposition using a CH 4 -H 2 gas mixture. The crystalline quality of the films was assessed through their ␣-particle detection performance, a property highly sensitive to film quality, by using a 5.5 MeV 241 Am source. A maximum collection efficiency of 70%, 50% being the average value, was obtained in a 115-m-thick sample after -particle irradiation ͑''priming effect''͒. Unprimed efficiency ϭ50% maximum, 30% average, was also obtained on other samples. The dependence of the efficiency and the resolving power on the external electric field was studied as well. The results are interpreted by means of a Monte Carlo analysis of the ␣-particle detection process. It is concluded that, in the priming process, a saturation occurs of deep defects limiting the as-grown detector performance, and charge collection distance is only limited by grain boundaries located close to the substrate side. Therefore, there is indication that further improvement can be reasonably obtained by increasing film thickness. © 1999 American Institute of Physics. ͓S0003-6951͑99͒02846-6͔ Synthetic diamond films grown by chemical-vapor deposition ͑CVD͒ have a great potential for applications in several fields, due to the many ͑mechanical, optical, electronic, etc.͒ exceptional properties of diamond. 1,2 However, their polycrystalline nature and the relatively high concentration of structural defects still represent a severe limitation for many applications. This is why the performance of several diamond-based devices currently under investigation 3-5 is strongly influenced by the growth and operating conditions.A particularly important and high-quality demanding application of diamond films is nuclear particle detection. 6,7 The high-energy gap of diamond results in a very low number of free carriers, leading to extremely low-leakage currents. Moreover, the radiation hardness and the hightemperature operation capability of such devices is strongly increased with respect to silicon-based detectors, a crucial feature in view of the operation of next-generation particle accelerators. 8 The main parameters assessing the quality of CVD diamond films to be used as particle detectors are the charge collection distance ͑CCD͒ and the efficiency, defined as follows. When an electron-hole pair is created by an ionizing particle in a parallel-plate detector of thickness ͑i.e., electrode spacing͒ L, it induces 9,10 in the external circuit a charge q c ϭex/L, x being the total distance the electron and hole move apart. The CCD is the average drift distance and is given by ␦ϭ͑ e ϩ h ͒ E,
͑1͒where e , h are the electron and hole mobilities, respectively, is the mobility weighted lifetime of electrons and holes, and E is the applied electric field. The efficiency is the ratio of the collected charge Q c to the total charge Q 0 generated by the ionizing particleThe link between and ␦ can be deduced from the HechtG being the penetration depth in L of the particles to be detected ͓for Eq. ͑3͒ we assum...