Surface Raman scattering of methanol, 1-propanol, 1-pentanol, and 1-butanethiol on in situ and emersed silver electrodes

Structure and electrochemical reactivity of 3-[tris(2-methoxyethoxy)silyl]-propanethiol adsorbed on silver surface

“…therein. The majority of experimental data on the structure and the nature of intermolecular interactions have been collected for monolayers of alkanethiols and di-n-alkyl disulfides on Au [2][3][4][5][6][7][8][9][10][11][12][13][14] and Ag [2,9,11,12,[14][15][16][17]. Alkylsilanes can also build mono-and multilayer films if the hydroxyl groups with which they can interact are present on the substrate surface [18].…”

Effect of different silver substrate on the SERS signal of sulfide adsorbent

“…1 They found that the surface products of thiophenol and phenyl disulfide on silver were identical and they were adsorbed in the same state. Sobocinske et al 2 studied alkylthiols at electrode surfaces using SERS and made comparisons between the surface interactions of alcohols and thiols. A silver surface shows an intense SERS effect.…”

Fourier-transform surface enhanced Raman scattering studies of molecular self-assembly of disulfides on metals and the application in adhesion promotion

“…These kinds of molecules are particularly useful in building up supermolecular structures on metals. Since much of the work has been on noble-metal surfaces and the symmetric disulfide stretches are IR inactive, many of the surface studies have used SERS as the spectroscopic tool [4][5][6][7][8][9].…”

“…Sobocinski and co-workers [5] have studied alkylthiols at electrode surfaces using SERS and have made comparisons between the surface interactions of alcohols and thiols. Meanwhile some studies indicating the phenomenon of surface-enhanced photochemical reaction have been reported [9].…”