Synthese, Struktur und Eigenschaften der Nonachloroditellur(IV)- und Tetrachlorohydroxotellur(IV)säure-Hydrate. Kristallstrukturen der Oxonium-Salze [H9O4]n[Te2Cl9]n und [H9O4][TeCl4OH ] · H2O/Synthesis, Structure and Properties of Nonachloroditellurous and Tetrachlorohydroxotellurous Acid Hydrates. Crystal Structures of the Oxonium Salts [H9O4]n[Te2Cl<su

Krebs, Bernt; Bonmann, S.; Gretenkord, K.

doi:10.1515/znb-1992-0118

Cited by 10 publications

(2 citation statements)

References 1 publication

Supporting

Mentioning

Contrasting

Order By: Relevance

“…An interaction with the oxygen atom O(1) of the cationic unit completes this coordination sphere to a highly distorted octahedron. The Te(1)´´´O(1)-distance is 2.727(4) A Ê (bond valence 0.13 [16] [9] shows the interactions to be weak. With its four terminal chlorine atoms Te(2) forms a w-trigonal bipyramidal fragment with the lone electron pair of Te(2) pointing towards Te(1).…”

Section: Structure Ofmentioning

confidence: 99%

See 1 more Smart Citation

[H3O · (Dibenzo-18-crown-6)][Te2Br9] and [H5O2][Te2Cl9] · 2 C4H8O2: Two New Oxonium Halotellurates(IV) Containing a Novel Type of [Te2X9]– Anions

Reich

Hasche

Bonmann

et al. 1998

Z. anorg. allg. Chem.

View full text Add to dashboard Cite

Red crystals of [H3O · (dibenzo‐18‐crown‐6)][Te2Br9] (1) were isolated from a solution of TeBr4 and dibenzo‐18‐crown‐6 in CH3CN containing a small amount of hydrobromic acid. The compound crystallizes in the triclinic space group P 1 with the cell dimensions a = 9.010(2), b = 13.403(3), c = 14.606(4) Å, α = 98.94(2)°, β = 100.40(2)°, and γ = 91.40(2)° (150 K). From a solution of TeCl4 in 1,4‐dioxane containing hydrochloric acid [H5O2][Te2Cl9] · 2 C4H8O2 (2) precipitates as colorless crystals in the orthorhombic space group Pnma with the cell dimensions a = 17.023(4), b = 13.389(4), and c = 10.900(3) Å (150 K). In both structures the [Te2X9]– anion (X = Cl, Br) consists of one TeX6 octahedron and one TeX5 square pyramidal unit connected by a common edge. In compound 1 the coordination sphere of the square pyramidal fragment is completed by a very weakly η6 bound benzo group of the cationic unit. In compound 2 an oxygen atom of the oxonium ion weakly interacts with the fivefold coordinated tellurium atom. The cationic units are a crown ether oxonium complex in 1 and a supramolecular 1,4‐dioxane‐oxonium network in 2.

show abstract

Section: Structure Ofmentioning

confidence: 99%

“…It consists of two distorted octahedral TeI 6 fragments sharing one face. Furthermore the compounds [PCl 4 ] n [TeCl 5 ] n [7, 8] and [H 9 O 4 ] n [Te 2 Cl 9 ] n[9] contain polymeric anionic species. The [TeCl 5 ] n n± anion consists of TeCl 6 octahedra connected by common edges.…”

mentioning

confidence: 99%

[H3O · (Dibenzo-18-crown-6)][Te2Br9] and [H5O2][Te2Cl9] · 2 C4H8O2: Two New Oxonium Halotellurates(IV) Containing a Novel Type of [Te2X9]– Anions

Reich

Hasche

Bonmann

et al. 1998

Z. anorg. allg. Chem.

View full text Add to dashboard Cite

show abstract

ChemInform Abstract: Synthesis, Structure and Properties of Nonachloroditellurous and Tetrachlorohydroxotellurous Acid Hydrates. Crystal Structures of the Oxonium Salts (H9O4)n(Te2Cl9)n and (H9O4)(TeCl4OH)×H2O.

Krebs¹,

Bonmann²,

Gretenkord³

1992

ChemInform

View full text Add to dashboard Cite

show abstract

Raman and ¹²⁵Te NMR spectroscopic evidence on the solvent extraction of tellurium(IV) species from HCl solutions

Baker

Taylor

1994

J Raman Spectroscopy

View full text Add to dashboard Cite

The Raman spectra of solutions of TeCl, in HCl up to 12 mol 1-' show a changing pattern of bands consistent with a mixture of complexes, including [TeC1,I2-and [TeCl,(OH)]-. High-field '"Te NMR spectra at 126.24 MHz of these aqueous solutions consist of a single band, showing that the TeIV species are in rapid equilibrium, which moves upfield within the range + 1550 to + 1400 ppm as the HCl concentration is increased. Solvent extraction with diethyl ether selects a single species from TeIV-HC1 solutions. This is identified as the complex acid HTeCl,(OH) by a Raman spectrum marked by v,(Te-Cl) = 289 cm-' and v ( T 4 ) = 667 cm-', and a characteristic '"Te resonance, 6 = 1448 ppm, wli2 = 80 Hz.

show abstract

Abstract: A norganisch-C hem isches In stitu t der W estfälischen W ilhelm s-U niversität M ünster, W ilhelm -K lem m -Straße 8 , D-4400 M ü n ster

Cited by 10 publications

References 1 publication

[H3O · (Dibenzo-18-crown-6)][Te2Br9] and [H5O2][Te2Cl9] · 2 C4H8O2: Two New Oxonium Halotellurates(IV) Containing a Novel Type of [Te2X9]– Anions

[H3O · (Dibenzo-18-crown-6)][Te2Br9] and [H5O2][Te2Cl9] · 2 C4H8O2: Two New Oxonium Halotellurates(IV) Containing a Novel Type of [Te2X9]– Anions

ChemInform Abstract: Synthesis, Structure and Properties of Nonachloroditellurous and Tetrachlorohydroxotellurous Acid Hydrates. Crystal Structures of the Oxonium Salts (H9O4)n(Te2Cl9)n and (H9O4)(TeCl4OH)×H2O.

Raman and ¹²⁵Te NMR spectroscopic evidence on the solvent extraction of tellurium(IV) species from HCl solutions

Contact Info

Product

Resources

About

Abstract: A norganisch-C hem isches In stitu t der W estfälischen W ilhelm s-U niversität M ünster, W ilhelm -K lem m -Straße 8 , D-4400 M ü n ster

Cited by 10 publications

References 1 publication

[H3O · (Dibenzo-18-crown-6)][Te2Br9] and [H5O2][Te2Cl9] · 2 C4H8O2: Two New Oxonium Halotellurates(IV) Containing a Novel Type of [Te2X9]– Anions

[H3O · (Dibenzo-18-crown-6)][Te2Br9] and [H5O2][Te2Cl9] · 2 C4H8O2: Two New Oxonium Halotellurates(IV) Containing a Novel Type of [Te2X9]– Anions

ChemInform Abstract: Synthesis, Structure and Properties of Nonachloroditellurous and Tetrachlorohydroxotellurous Acid Hydrates. Crystal Structures of the Oxonium Salts (H9O4)n(Te2Cl9)n and (H9O4)(TeCl4OH)×H2O.

Raman and 125Te NMR spectroscopic evidence on the solvent extraction of tellurium(IV) species from HCl solutions

Contact Info

Product

Resources

About

Raman and ¹²⁵Te NMR spectroscopic evidence on the solvent extraction of tellurium(IV) species from HCl solutions