Synthesis and characterization of complexes of PdII and PtII containing the iminophosphorane ligand Ph3PNCN

Synthesis, Structure, Reactivity, and Catalytic Activity of C,N‐ and C,N,N‐Orthopalladated Iminophosphoranes

“…In the case of Pd, mixtures of the corresponding cis-and trans-[Cl 2 Pd(N-ligand) 2 ] derivatives were obtained; [29,30] in the case of platinum only decomposition to black Pt 0 was observed. Due to the lack of reactivity of these iminophosphoranes, they were not further investigated.…”

“…In this context, we have recently reported some aspects of the chemistry of the α-stabilized iminophosphoranes Ph 3 tate or chelate bidentate ligands towards Pd II and Pt II complexes using different donor atoms. [29,30] However, the synthesis of orthometallated aryl complexes derived from iminophosphoranes is still scarcely represented, as well as the properties of the resulting complexes (reactivity, catalytic performance), [31][32][33][34][35][36] although very recently relevant contributions have appeared in the literature. [37,38] With the aim of expanding the scope of this type of orthometallated derivatives, and also to gain more insight into their chemical behaviour, we have studied the reactivity of several iminophosphoranes towards Pd II and Pt II metallating reagents.…”

Synthesis and thermal behavior of dimethyl scandium complexes featuring anilido-phosphinimine ancillary ligands

“…1 H NMR (C 6 D 6 ): d 7.61 (m, 4H, m-P-(C 6 H 5 ) 2 ), 7. 5H,PNC 6 H 4 ,NC 6 H 3 ), 7.07-6.88 (m, 10H, o,p-P(C 6 H 5 ) 2 , PNC 6 H 4 , PC 6 H 4 N), 6.21 (m,1H,PC 6 H 4 N),6.27 (m,1H,PC 6 ,9.61;N,5.34. Found C,77.97;H,9.52,N,5.30%.…”

“…1 H NMR (C 6 D 6 ): d 9.06 (s,1H,NH),7.73 (m,4H, 2 ), 6H,PNC 6 H 4 ,NC 6 H 3 ), 7.02-6.97 (m, 8H, NC 6 H 3 , o,p-P(C 6 H 5 ) 2 , NC 6 H 3 , PC 6 H 4 N), 6.4 (m,2H,PC 6 H 4 N), 3.77 (sp, 2H, CHMe 2 ), 3.13 (sp, 2H, CHMe 2 ), 1.11 (d,6H,CH(CH 3 ) 2 ), 1.03 (d,12H,CH(CH 3 ) 2 ), 0.95 (d,6H,CH(CH 3 ) 2 ). 13 C NMR (C 6 D 6 ): d 154.4 (1 quaternary aromatic), 148.0 (1Ph), 144.2 (1 quaternary aromatic), 143.2 (1Ph), 135.…”

“…1 H NMR (C 6 D 6 ): d 9.03 (s, 1H, NH), 7.87 (m, 4H, m-P-(C 6 H 5 ) 2 ), 7.31 (m,1H,PNC 6 H 4 ),3H,NC 6 H 3 ), 7.02-6.87 (m, 10H, o,p-P(C 6 H 5 ) 2 , PNC 6 H 4 , PC 6 H 4 N), 6.44 (m,1H,PC 6 H 4 N), 6.27 (m,1H,PC 6 H 4 N), 4.13 (sp, 1H, CHMe 2 ), 3.00 (sp, 2H, CHMe 2 ), 1.35 (d,6H,CH(CH 3 ) 2 ), 0.99 (d,6H,CH(CH 3 ) 2 ), 0.84 (d,6H,CH(CH 3 ) 2 ). 13 128.6,126.1,125.8,124.1,121.1,118.9,116.0,113.3 (8Ph),112.1,110.8 (2 quaternary aromatic) 28.6 (CHMe 2 ), 28.4 (CHMe 2 ), 24.3 (CH(CH 3 ) 2 ), 23.8 (CH(CH 3 ) 2 ), 23.2 (CH(CH 3 ) 2 ).…”