Synthesis and characterization of UV-absorbing fluorine-silicone acrylic resin polymer

Lei, Huibin; He, Deliang; Guo, Yanni; Tang, Yining; Huang, Haihong

doi:10.1016/j.apsusc.2018.02.134

Cited by 64 publications

(17 citation statements)

References 24 publications

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“…S was present in the resin only as -SO 3 H (Figure 2C), [18] and O was present as -SO 3 H and S=O (Figure 2D). [19] In addition, the ratio of the area of the S=O peak to the S-O peak was approximately 2:1, which further confirmed that O was mainly present as -SO 3 H in the resin.…”

Section: Xps Analysismentioning

confidence: 57%

Mechanism and kinetics study of Mg²⁺ removal from wet‐process phosphoric acid by Sinco‐430 resin

Yan

et al. 2021

Can J Chem Eng

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The reaction mechanism and kinetics of Sinco-430 cation exchange resin removing Mg 2+ from wet-process phosphoric acid (WPA) were studied. Fourier transform infrared and X-ray photoelectron spectroscopy analyses revealed that the main functional group of the resin that combined with Mg 2+ ions was -SO 3 H. To investigate the most suitable conditions for Mg 2+ removal, the operating parameters that could affect Mg 2+ removal were studied. The results demonstrated that under optimal conditions (T = 50 C, solid to liquid mass ratio = 0.3, and P 2 O 5 content = 20 wt.%) the reaction reached equilibrium in 8 min and Mg 2+ removal rate reached 59.09%. The kinetic model and activation energy of the reaction were second-order and 19.11 kJ/mol according to kinetic analysis, respectively. The diffusion model of Mg 2+ removal was determined as pore diffusion according to the comparison of three different diffusion models. H 3 PO 4 was recovered using deionized water and Mg 2+ was removed from the loading resin with 20 wt.% H 2 SO 4 . In addition, after eight loading/regeneration cycles, the Mg 2+ removal ability of the Sinco-430 resin remained the same. The Mg 2+ removal rate in a fixed-bed reactor was 98.83%, higher than that obtained in a continuous stirred-tank reactor.

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Section: Xps Analysismentioning

confidence: 57%

Mechanism and kinetics study of Mg²⁺ removal from wet‐process phosphoric acid by Sinco‐430 resin

Yan

et al. 2021

Can J Chem Eng

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“…In total, from starting to 30th cycle, the adhesive strength is remained at 1.82 MPa for S3 but decreased from 1.92 to 1.56 MPa for S1 (relatively decreased 18.7%). This relatively maintained adhesive strength for S3 and relatively decreased for S1 are attributed the contribution of aging-resistance from P12FMA in S3. , It further reveals that the fluorinated groups do not affect the bonding strength between epoxy group and the substrate and therefore maintain the strong durability adhesion of S3.…”

Section: Resultsmentioning

confidence: 79%

“…This relatively maintained adhesive strength for S3 and relatively decreased for S1 are attributed the contribution of aging-resistance from P12FMA in S3. 44,45 It further reveals that the fluorinated groups do not affect the bonding strength between epoxy group and the substrate and therefore maintain the strong durability adhesion of S3.…”

Section: Adhesive Strength and Durabilitymentioning

confidence: 95%

Hydrophobic and Durable Adhesive Coatings Fabricated from Fluorinated Glycidyl Copolymers Grafted on SiO₂ Nanoparticles

Wang

Pan

et al. 2018

ACS Appl. Nano Mater.

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To obtain durable adhesive, highly hydrophobic, and thermostable coatings, novel fluorinated glycidyl copolymers grafted on SiO2 nanoparticles were prepared by SiO2–Br initiating covalent adhesion of glycidyl methacrylate (GMA) and low surface free energy of dodecafluoroheptyl methacrylate (12FMA) via surface initiated atom transfer radical polymerization. In tetrahydrofuran solution, the obtained random-structured SiO2-g-(PGMA-co-P12FMA) behaves with 120 ± 10 nm core–shell morphology as SiO2-core (110 ± 10 nm) and (PGMA-co-P12FMA) shell (8 ± 2 nm). The films cast by these core–shell particles reveal stronger hydrophobic surfaces (SAC = 114–119°), higher resistance to water absorption (Δm = 2478 ng·Hz–1·cm–2), and harder viscoelasticity (ΔD/Δf = −0.379) compared to the SiO2-g-PGMA film (SAC = 90°, Δm = 6153.7 ng·Hz–1·cm–2, and ΔD/Δf = −0.271) due to the accumulated fluorine-rich surface and increased surface roughness. The introduction of antiaging P12FMA obviously improves the durability of adhesive strength of SiO2-g-(PGMA-co-P12FMA) (1.82 MPa) compared with that of SiO2-g-PGMA (decreased from 1.92 to 1.56 MPa) during the humidity thermal aging cycles. Meanwhile, SiO2-g-(PGMA-co-P12FMA) displays thermostability higher than that of both SiO2–PGMA and PGMA-co-P12FMA, attributed to the contribution of SiO2 and P12FMA. Therefore, it is believed that SiO2-g-(PGMA-co-P12FMA) could be an excellent potential candidate for highly hydrophobic and durable adhesive coatings.

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“…Silicone has been known as an inorganic–organic hybrid polymer material featured with a series of properties such as good chemical and thermal ability, weather-resistance, low friction coefficient, low surface energy, and nonstick behavior [20,21,22,23,24]. It has also been widely used as an additive agent to improve the properties of polymer materials, such as thermal ability [25,26,27] and weather-resistance [28,29]. As a kind of multifunctional photoinitiator, silicone-containing photoinitiator could also endow some specific properties on the photocured materials, such as reducing the critical surface tension of the crosslinked films [30,31].…”

Section: Introductionmentioning

confidence: 99%

Silicone-Thioxanthone: A Multifunctionalized Visible Light Photoinitiator with an Ability to Modify the Cured Polymers

Liao

Xiong

et al. 2019

Polymers

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A silicone-thioxanthone (STX) visible light photoinitiator was prepared by the nucleophilic substitution reaction of 2-[(4-hydroxybenzyl)-(methyl)-amino]-9H-thioxanthen-9-one (TX-HB) and γ-chloropropylmethylpolysiloxane-co-dimethyl-polysiloxane (PSO-Cl). Its structure was confirmed by 1H NMR, 13C NMR, FTIR, UV-vis and GPC. The photopolymerization kinetics of 1, 6-Hexanedioldiacrylate (HDDA) and trimethylolpropane triacrylate (TMPTA) initiated by STX confirmed that STX is an efficient photoinitiator. Its visible light photolysis experiment and the photopolymerization kinetics studies implied that a possible synergistic effect existed between two adjacent thioxanthone groups. Moreover, a higher migration stability was revealed in STX than 2-benzyl (methyl) amino-9H-thioxanthen-9-one (TX-B). STX could change the surface property of the cured film of polyurethane diacrylate prepolymer (PUA) from hydrophilic to hydrophobic, as well as change the thermal stability of the polymer network. Meanwhile, it could improve the resistance against water and acid. Thus, STX is an effective multifunctionalized photoinitiator.

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Synthesis and characterization of UV-absorbing fluorine-silicone acrylic resin polymer

Cited by 64 publications

References 24 publications

Mechanism and kinetics study of Mg²⁺ removal from wet‐process phosphoric acid by Sinco‐430 resin

Mechanism and kinetics study of Mg²⁺ removal from wet‐process phosphoric acid by Sinco‐430 resin

Hydrophobic and Durable Adhesive Coatings Fabricated from Fluorinated Glycidyl Copolymers Grafted on SiO₂ Nanoparticles

Silicone-Thioxanthone: A Multifunctionalized Visible Light Photoinitiator with an Ability to Modify the Cured Polymers

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Synthesis and characterization of UV-absorbing fluorine-silicone acrylic resin polymer

Cited by 64 publications

References 24 publications

Mechanism and kinetics study of Mg2+ removal from wet‐process phosphoric acid by Sinco‐430 resin

Mechanism and kinetics study of Mg2+ removal from wet‐process phosphoric acid by Sinco‐430 resin

Hydrophobic and Durable Adhesive Coatings Fabricated from Fluorinated Glycidyl Copolymers Grafted on SiO2 Nanoparticles

Silicone-Thioxanthone: A Multifunctionalized Visible Light Photoinitiator with an Ability to Modify the Cured Polymers

Contact Info

Product

Resources

About

Mechanism and kinetics study of Mg²⁺ removal from wet‐process phosphoric acid by Sinco‐430 resin

Mechanism and kinetics study of Mg²⁺ removal from wet‐process phosphoric acid by Sinco‐430 resin

Hydrophobic and Durable Adhesive Coatings Fabricated from Fluorinated Glycidyl Copolymers Grafted on SiO₂ Nanoparticles