Synthesis and crystal structures of two iron derivatives of permethylcyclopentasilane

Coordination chemistry of Si5Cl10 with organocyanides

“…Si-Si distances within the Si 5 ring are 2.34-2.35 A ˚in 1 which is slightly shorter than those observed in 2 (2.36-2.37 A ˚). This small variation in bond length may be attributed to differences 10 The C N bond length in 1 (1.106 A ˚) is slightly shorter than for free MeCN (1.16 A ˚)11 while those for 2 (1.15 and 1.14 A ˚) are very close to the calculated C N distance for PhCN (1.156 A ˚). 11 It is known that the C N bond becomes shorter upon coordination and the values observed in this study fall within the typical range (i.e., 1.11-1.15 A ˚).…”

Extremely bulky secondary phosphinoamines as substituents for sterically hindered aminosilanes

“…To date, only mono-aryl substituted cyclic, five-membered chlorosilanes have been structurally characterized, 22 and other related five-membered cyclic silianes were obtained by different synthetic approaches. 27 The molecular structures of 11 and 12 were successfully determined by single crystal XRD (Fig. 5).…”

Reactions of Hydrosilanes with Transition-Metal Complexes: Formation of Stable Transition-Metal Silyl Compounds

“…Structural data reported for silyl−transition-metal complexes prepared from hydrosilanes and that include only those derivatives with “classical” M−Si, M−H, and/or Si−H bonds are summarized in Table . − …”

“…Si(Fe,Ru,Os) bonds prepared by other methods or preceding 1980 and structurally characterized. SiFe: 2.218(2); 2.222(3); , 2.224(1); 2.2277(14); 2.230(2); 2.2330(14); 2.249(1); , 2.249(3); 2.252(3); 2.258(1); 2.260(6); 2.262(2); , 2.262(1); 2.263(1); 2.263(2), 2.264(2); 2.264(2); 2.265(1); 2.266(3); 2.267(1); 2.268(8); 2.271(4); 2.275(2); 2.278(1); 2.280(3); 2.281(4); 2.285(3); 2.286(5); 2.286(1); 2.287(2); 2.290(3); 2.294(1); 2.296(2); 2.297(3); 2.301(1); 2.303(1); 2.307(1); 2.307(2); 2.310(1); 2.322(1); 2.311(2); 2.311(3); 2.3l3(6); 2.315(2); 2.316(13); 2.322(4); 2.325(3); 2.326(3); 2.327(3); 2.328(1); 2.33(1); 2.330(2); 2.338(4); 2.339(2); 2.339(1); 2.341(2); 2.346; 2.347(1); 2.350(1); 2.354(2); 2.356; 2.356(1); 2.357(3); , 2.364(5); 2.365(2); 2.366(2); 2.366(1); 2.375(2); 2.378(1);…”