2018
DOI: 10.1016/j.eurpolymj.2017.11.042
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Synthesis and polymerization of vinylcyclopropanes bearing urethane groups for the development of low-shrinkage composites

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Cited by 22 publications
(20 citation statements)
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“…Within mixture UDT_43 the shrinkage force (−F N ) changed from 21 to 15 N (a decrease of 15%), while reaching high overall DBC. This was most likely the result of a combination of the CTA together with its high molecular weight causing significantly lower network density at the gel point …”
Section: Resultsmentioning
confidence: 99%
“…Within mixture UDT_43 the shrinkage force (−F N ) changed from 21 to 15 N (a decrease of 15%), while reaching high overall DBC. This was most likely the result of a combination of the CTA together with its high molecular weight causing significantly lower network density at the gel point …”
Section: Resultsmentioning
confidence: 99%
“…Moszner, Liska and coworkers investigated the photocuring of vinylcyclopropane-based composites as alternative to methacrylate-based dental fillings [ 51 , 52 , 53 ]. The synthetic focus was directed on various vinylcyclopropane monomers, which contain similar structural units like in commonly used acrylate-based monomers such as urethane dimethacrylate UDMA and tri(ethylene glycol) dimethacrylate TEGDMA ( Figure 8 ).…”
Section: Expanding Cycloalkanes and Cycloalkenesmentioning
confidence: 99%
“…Notably, in this context, bifunctional monomers, of which one of the two functionalities can be cured upon volumetric expansion, have been evaluated for applicability in novel product generations most recently. Prominent research foci comprise photopolymerizations with low or no volumetric shrinkage during curing [ 36 , 50 , 53 , 58 , 59 , 60 , 90 , 91 , 92 , 93 , 94 , 95 , 128 , 129 ], dental fillings with low or no volumetric shrinkage during curing [ 21 , 75 , 98 , 100 , 101 , 102 , 111 ] and the 3D printing with unrivaled alignment of the geometry of the printed object with the CAD drawing [ 51 , 73 ].…”
Section: Applicability Of Expanding Monomers In Novel Products Andmentioning
confidence: 99%
“…VCPs undergo not only radical homopolymerizations but also copolymerizations with other VCPs and conventional vinyl monomers. [15][16][17][18][19][20][21] Besides, it is well known that the radical thiol-ene reaction of vinyl compounds proceeds efficiently and selectively even in the presence of various functional groups. [22,23] The vinyl group of VCPs also reacts readily with thiols (Scheme 1b).…”
Section: Introductionmentioning
confidence: 99%