Synthesis and properties of a liquid oligomeric cyanate ester resin

Laskoski, Matthew; Dominguez, Dawn D.; Keller, Teddy M.

doi:10.1016/j.polymer.2006.03.097

Cited by 35 publications

(36 citation statements)

References 32 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…It has been pointed out that CE monomers with lower melting point aids processing. [21][22][23] The present study also explores the thermal, dynamic and hydrolytic properties of unexplored CE 1,1-bis(4-cyanatophenyl)cyclohexane (BPZCN). The thermal and thermomechanical properties and moisture absorption behavior of BPC15CN and BPZCN resins are compared with those of polycyanurate prepared from the commercially available CE monomer, namely 2,2-bis(4-cyanatophenyl) propane, and the results were discussed.…”

Section: Introductionmentioning

confidence: 99%

Cyanate ester resins containing pentadecyl-substituted cyclohexyl moiety: Synthesis, curing and structure–property relationship

Kulkarni

Tawade

Wadgaonkar

2012

High Performance Polymers

View full text Add to dashboard Cite

Cyanate ester (CE) monomers containing pentadecyl-substituted cyclohexyl moieties such as 1,1-bis(4-cyanatophenyl) 3-pentadecylcyclohexane and 1,1-bis(4-cyanatophenyl) cyclohexane were synthesized and characterized by Fourier transform infrared, proton-nuclear magnetic resonance ( 1 H-NMR) and carbon-nuclear magnetic resonance ( 13 C-NMR) spectroscopies as well as differential scanning calorimetry (DSC). Both 1,1-bis(4-cyanatophenyl) 3-pentadecylcyclohexane and 1,1-bis(4-cyanatophenyl) cyclohexane exhibited better processability coupled with lower melting points, lower cure onset with broad cure exotherm than the commercially available CE monomer, namely, 2,2-bis(4-cyanatophenyl) propane. Glass transition temperatures of cured 2,2-bis(4-cyanatophenyl) propane, 1,1-bis(4-cyanatophenyl) cyclohexane and 1,1-bis(4-cyanatophenyl) 3-pentadecylcyclohexane were observed to be 288 C, 302 C and 160 C, respectively. Cured 1,1-bis(4-cyanatophenyl) cyclohexane displayed higher storage modulus (1.59 Â 10 9 Pa) than 1,1-bis(4-cyanatophenyl) 3-pentadecylcyclohexane (1.07 Â 10 9 Pa) and 2,2-bis(4-cyanatophenyl) propane (1.39 Â 10 9 Pa). The order of thermal stability of cured polycyanurates was found to be 2,2-bis(4-cyanatophenyl) propane > 1,1-bis(4-cyanatophenyl)cyclohexane > 1,1-bis(4-cyanato phenyl) 3-pentadecylcyclohexane. The moisture absorption of cured resins derived from 1,1-bis(4-cyanatophenyl) 3-pentadecyl cyclohexane and 1,1-bis(4-cynatophenyl)cyclohexane was found to be lower than that of 2,2-bis(4-cynatophenyl) propane implying the role of pentadecyl substituent and/or cyclohexyl moiety in imparting hydrophobicity to the polycyanurates.

show abstract

Section: Introductionmentioning

confidence: 99%

Cyanate ester resins containing pentadecyl-substituted cyclohexyl moiety: Synthesis, curing and structure–property relationship

Kulkarni

Tawade

Wadgaonkar

2012

High Performance Polymers

View full text Add to dashboard Cite

show abstract

“…7,8 However, its thermal property needs to be improved to meet restrict requirements by next generation products for aerospace and aviation industries. [9][10][11] Many methods have been developed to modify CE resin, and some good results have been achieved, but it is found to be difficult to obtain a resin system with both thermal and dielectric properties; in other words, the improvement of thermal resistance is generally based on decreasing the dielectric property of original CE resin.…”

Section: Introductionmentioning

confidence: 99%

Novel high‐performance wave‐transparent aluminum phosphate/cyanate ester composites

Sun

Huang

et al. 2011

J of Applied Polymer Sci

View full text Add to dashboard Cite

Advanced wave-transparent composites are the key materials for many cutting-edge industries including aviation and aerospace, which should have outstanding heat resistance, low dielectric constant and loss as well as good mechanical properties. A novel kind of high-performance wave-transparent composites based on surface-modified aluminum phosphate AlPO 4 (KH-550) and cyanate ester (CE) was first developed. The dielectric and dynamic mechanical properties of AlPO 4 (KH-550)/CE composites were investigated intensively. Results show that AlPO 4 (KH-550)/ CE composites have decreased dielectric loss and higher storage moduli than pure CE resin; in addition, the composites with suitable AlPO 4 (KH-550) concentration remain the outstanding thermal property and low dielectric constant of pure CE resin. The reasons attributing to these results are discussed from the effects of AlPO 4 (KH-550) on the key aspects such as morphology, curing mechanism, and interfacial adhesion of composites.

show abstract

“…7) and styrene-UP copolymerization (Fig. 8) [11][12][13][14]. After the curing process was launched by decomposing of TBPB, an increase of the resin temperature caused by the reaction exotherm may occur, which accelerated the curing reaction of UP resins.…”

Section: Curing Process Of Rnmpmentioning

confidence: 99%

Manufacturing process of reproduction plate by nonmetallic materials reclaimed from pulverized printed circuit boards

Guo

Cao

et al. 2009

Journal of Hazardous Materials

View full text Add to dashboard Cite

Synthesis and properties of a liquid oligomeric cyanate ester resin

Cited by 35 publications

References 32 publications

Cyanate ester resins containing pentadecyl-substituted cyclohexyl moiety: Synthesis, curing and structure–property relationship

Cyanate ester resins containing pentadecyl-substituted cyclohexyl moiety: Synthesis, curing and structure–property relationship

Novel high‐performance wave‐transparent aluminum phosphate/cyanate ester composites

Manufacturing process of reproduction plate by nonmetallic materials reclaimed from pulverized printed circuit boards

Contact Info

Product

Resources

About