Synthesis and properties of fluorosilicon compounds for protection of cultural monuments from harmful environmental exposure

Yarosh, A. A.; Krukovsky, S. P.; Sakharov, A. M.; Popovich, M.Y. Yu; Kotov, V. M.; Pryakhina, T. A.

doi:10.1007/s11172-014-0467-0

Russ Chem Bull

2014

DOI: 10.1007/s11172-014-0467-0

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Synthesis and properties of fluorosilicon compounds for protection of cultural monuments from harmful environmental exposure

A. A. Yarosh

S. P. Krukovsky

A. M. Sakharov

et al.

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“…Triethoxysilylpropylamides of perfluorooxaalkylenecarboxylic acids RFCOHN(CH2)3Si(OR)3, triethoxysilylpropylamide of perfluoro-2,5-dimethyl-3,6-dioxanonanoic acid (Fluorosam-39, F-39) particularly, were used [1][2][3][4] for hydro-and desensitization of chalk-stone, marble, plaster, brick, paper, wood and other materials.…”

mentioning

confidence: 99%

Thermal Transformations of Polymer of Perfluoro-2,5-dimethyl-3,6-dioxanonanoic Acid Triethoxysilylpropylamide

Krukovsky¹

2017

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Polymerization of perfluoro-2,5-dimethyl-3,6-dioxanonanoic acid triethoxysilylpropylamide (Fluorosam-39) was studied. It was found out that the polymer's macromolecule contains two kinds of structure fragments, one of which takes part in the ramified parts of macromolecule formation, the other onein the line sections of macromolecule formation. The polymer has an amorphous structure and does not dissolve neither in organic, nor in organofluorine solvents. It was stated that at thermal destruction the weakest point is an amide bond from which starts the polymer's destruction, leading to the monohydro-derivative-2Hheptadecafluoro-5-methyl-3,6-dioxanonane and a coke residue formation.

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mentioning

confidence: 99%

Thermal Transformations of Polymer of Perfluoro-2,5-dimethyl-3,6-dioxanonanoic Acid Triethoxysilylpropylamide

Krukovsky¹

2017

FNotes

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Use of freezing techniques for increasing the output of ultralow density laser targets

2016

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Benzene Adsorption on Nanoporous Silica Gels with Grafted Polyfluoroalkyl Layers and the Wettability

Roshchina

Shoniya

Ткаченко

et al. 2021

Russ. J. Phys. Chem.

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Synthesis and properties of fluorosilicon compounds for protection of cultural monuments from harmful environmental exposure

Cited by 3 publications

References 2 publications

Thermal Transformations of Polymer of Perfluoro-2,5-dimethyl-3,6-dioxanonanoic Acid Triethoxysilylpropylamide

Thermal Transformations of Polymer of Perfluoro-2,5-dimethyl-3,6-dioxanonanoic Acid Triethoxysilylpropylamide

Use of freezing techniques for increasing the output of ultralow density laser targets

Benzene Adsorption on Nanoporous Silica Gels with Grafted Polyfluoroalkyl Layers and the Wettability

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