Synthesis, characterization and electroluminescence of B(III) compounds: BPh2(2-(2-quinolyl)naphtho[b]imidazolato) and BPh2(2-(2-quinolyl)benzimidazolato)

Chen, Tsun‐Ren; Chien, Rong-Hong; Yeh, An-Chi; Chen, Jhy‐Der

doi:10.1016/j.jorganchem.2005.12.060

Cited by 28 publications

(11 citation statements)

References 29 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…For instance, 5 a 39 was used as pure emitting layer in devices with a brilliance around 1000 cd m −2 (Figure 35). Other N,N borate complexes such as 15 a 144 and 16 b 55 are not electroactive by themselves but have been used as dopants in standard devices exhibiting then a brilliance of respectively 320 and 457 cd m −2 .…”

Section: Electroluminescent Devicesmentioning

confidence: 99%

A Dication Cross‐Linked Composite Anion‐Exchange Membrane for All‐Vanadium Flow Battery Applications

Zhang

2013

ChemSusChem

View full text Add to dashboard Cite

Multidisciplinary research on novel organic luminescent dyes is propelled by potential applications in plastic electronics and biomedical sciences. The construction of sophisticated fluorescent dyes around a tetrahedral boron(III) center is a particular approach that has fueled the creativity of chemists. Success in this enterprise has been readily achieved with simple synthetic protocols, the products of which display unusual spectroscopic behavior. This account is a critical review of recent advances in the field of boron(III) complexes (excluding BODIPYs and acetylacetonate boron complexes) involving species displaying similar coordination features, and we outline their potential development in several disciplines.

show abstract

Section: Electroluminescent Devicesmentioning

confidence: 99%

A Dication Cross‐Linked Composite Anion‐Exchange Membrane for All‐Vanadium Flow Battery Applications

Zhang

2013

ChemSusChem

View full text Add to dashboard Cite

show abstract

“…In 2006, Tsun-Ren Chen’s group realized 2-(1 H -benzo[d]imidazol-2-yl)quinoline ( 103 ) and 2-(quinolin-2-yl)-1 H -naphtho[2,3-d]imidazole ( 104 ) reacting with triphenylboron to generate diphenylboron complexes ( 105 – 106 , 30–35%) [ 53 ], as shown in Scheme 20 . The product ( 105 ) could be used as organometallic emitting material in organic light-emitting diodes (OLEDs).…”

Section: Quinoline-based Derivatives As Bidentate Ligandmentioning

confidence: 99%

“…The data presented in this study are openly available in references [ 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14 , 15 , 16 , 17 , 18 , 19 , 20 , 21 , 22 , 23 , 24 , 25 , 26 , 27 , 28 , 29 , 30 , 31 , 32 , 33 , 34 , 35 , 36 , 37 , 38 , 39 , 40 , 41 , 42 , 43 , 44 , 45 , 46 , 47 , 48 , 49 , 50 , 51 , 52 , 53 , 54 , 55 , 56 , …”

unclassified

Recent Progress on Synthesis of N,N′-Chelate Organoboron Derivatives

et al. 2021

View full text Add to dashboard Cite

N,N′-chelate organoboron compounds have been successfully applied in bioimaging, organic light-emitting diodes (OLEDs), functional polymer, photocatalyst, electroluminescent (EL) devices, and other science and technology areas. However, the concise and efficient synthetic methods become more and more significant for material science, biomedical research, or other practical science. Here, we summarized the organoboron-N,N′-chelate derivatives and showed the different routes of their syntheses. Traditional methods to synthesize N,N′-chelate organoboron compounds were mainly using bidentate ligand containing nitrogen reacting with trivalent boron reagents. In this review, we described a series of bidentate ligands, such as bipyridine, 2-(pyridin-2-yl)-1H-indole, 2-(5-methyl-1H-pyrrol-2-yl)quinoline, N-(quinolin-8-yl)acetamide, 1,10-phenanthroline, and diketopyrrolopyrrole (DPP).

show abstract

“…Beispielsweise wurde 5 a 39 als reine emittierende Schicht in Bauelementen mit einer Helligkeit von etwa 1000 cd m −2 eingesetzt (Abbildung 35). Andere N,N‐Borat‐Komplexe, wie 15 a 144 und 16 b ,55 sind selbst nicht elektroaktiv, werden aber als Dotierstoffe in standardmäßigen Bauelementen verwendet, die dann eine Helligkeit von 320 bzw. 457 cd m −2 aufweisen.…”

Section: Elektrolumineszierende Bauelementeunclassified

Lumineszierende Materialien: Fixierung von π‐konjugierten und heterocyclischen Liganden mit Bor(III)

et al. 2014

View full text Add to dashboard Cite

Die multidisziplinäre Forschung zu neuen organischen Lumineszenzfarbstoffen wird durch mögliche Anwendungen in der Kunststoffelektronik und Biomedizin vorangetrieben. Die Anordnung ausgeklügelter Fluoreszenzfarbstoffe um ein tetraedrisches Bor(III)‐Zentrum herum ist eine besondere Herangehensweise, die die Kreativität der Chemiker herausfordert. Erfolgreich sind dabei einfache Synthesemethoden, die zu Produkten mit ungewöhnlichem spektroskopischem Verhalten führen. Dieser Kurzaufsatz liefert eine kritische Betrachtung neuerer Fortschritte auf dem Gebiet solcher Bor(III)‐Komplexe (unter Ausschluss von BODIPY‐Verbindungen und Acetylacetonat‐Bor‐Komplexen), die Spezies mit ähnlichen Koordinationsmerkmalen umfassen, und prognostiziert die mögliche Entwicklung dieser Komplexe in verschiedenen Fachbereichen.

show abstract

Synthesis, characterization and electroluminescence of B(III) compounds: BPh2(2-(2-quinolyl)naphtho[b]imidazolato) and BPh2(2-(2-quinolyl)benzimidazolato)

Cited by 28 publications

References 29 publications

A Dication Cross‐Linked Composite Anion‐Exchange Membrane for All‐Vanadium Flow Battery Applications

A Dication Cross‐Linked Composite Anion‐Exchange Membrane for All‐Vanadium Flow Battery Applications

Recent Progress on Synthesis of N,N′-Chelate Organoboron Derivatives

Lumineszierende Materialien: Fixierung von π‐konjugierten und heterocyclischen Liganden mit Bor(III)

Contact Info

Product

Resources

About