Synthesis, crystal structures and biological activities of palladium(II) complexes of benzimidazole and 2-methylbenzimidazole

Sadaf, Hina; Imtiaz‐ud‐Din,; Fettouhi, Mohammed; Fazal, Atif; Ahmad, Saeed; Farooqi, Bilal Ahmad; Nadeem, Shafqat; ul-Haq, Ihsan; Ahmad, Waqar

doi:10.1016/j.poly.2019.06.025

Cited by 17 publications

(10 citation statements)

References 44 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In the presence of catalysts synthesized from 1-4/Pd(OAc)2, various Suzuki-Miyaura coupling products (5)(6)(7)(8) were obtained from the reaction of 4-chloronitrobenzene, 4-chloroanisole or 4chlorotoluene with phenylboronic acid and 4chloroacetophenone with tianaften-2-boronic acid. These are 1-phenyl-4-nitrobenzene (5), 1-phenyl-4-methoxybenzene (6), 1-phenyl-4-methylbenzene (7) and 1-(4-(benzo[b]thiophen-2-yl)phenyl ethanone (8).…”

Section: Resultsmentioning

confidence: 99%

“…Compounds containing benzimidazole nucleus demonstrate a wide variety of biological activity properties such as anticancer, antitubercular antimicrobial, antifungal, antioxidant, antidiabetic and etc [1][2][3][4][5][6][7][8][9][10][11][12][13]. On the other hand, heterocyclic benzimidazole derivatives have different application area and can be used as catalysts [14][15][16] and sensors [17,18].…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Suzuki-Miyaura Çapraz Eşleşme Reaksiyonunda Katalizör Olarak Heterosiklik Bileşiklerin Uygulanması

Akkoç

2019

Cumhuriyet Science Journal

View full text Add to dashboard Cite

Four different benzimidazolium salts (1-4) were prepared in three steps at 80 o C and their structures were elucidated using spectroscopic methods. The compounds (1-4) obtained were tested in in situ medium as catalyst in the carbon-carbon (C-C) bond formation reactions of two different boronic acid derivatives with various aryl halides in the presence of palladium acetate (PdOAc)2 and sodium tertiarybutoxide (NaOBu t) as a base. With this reaction, four coupling products (5-8) were synthesized in different yields ranging from 11 to 93%. Compound 2 from the carbene precursors tested in the Suzuki-Miyaura cross-coupling reaction was found to be a more effective catalyst candidate than others.

show abstract

Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Suzuki-Miyaura Çapraz Eşleşme Reaksiyonunda Katalizör Olarak Heterosiklik Bileşiklerin Uygulanması

Akkoç

2019

Cumhuriyet Science Journal

View full text Add to dashboard Cite

show abstract

“…It can be noted that with lengthening of the substituent, the proportion of H⋯H interactions increases. [53]; LOFTOS: bis(iodo)-bis(2-methyl-1Hbenzimidazole)-palladium(II) [53]; XIKZON: Dichlorido[bis(2-hexylsulfanyl)-1H-benzimidazole-κN 3 ]palladium(II) [54]; ZIWTEH: trans-Dichlorido-bis(1H-benzimidazole)-palladium(II) [55].…”

Section: Hirshfeld Surface Analysismentioning

confidence: 99%

“…2021, 11, x FOR PEER REVIEW 11 of 15 [53]; LOFTOS: bis(iodo)-bis(2-methyl-1H-benzimidazole)-palladium(II) [53]; XIKZON: Dichlorido[bis(2-hexylsulfanyl)-1H-benzimidazole-κN 3 ]palladium(II) [54]; ZIWTEH: trans-Dichloridobis(1H-benzimidazole)-palladium(II) [55].…”

Section: Hirshfeld Surface Analysismentioning

confidence: 99%

“…Percentage contributions of contacts to the Hirschfeld surface in structures 1 and taken from CSD. LOF-TIM: bis(1H-benzimidazole)-(dibromo)-palladium(II) dimethyl sulfoxide solvate[53]; LOFTOS: bis(iodo)-bis(2-methyl-1Hbenzimidazole)-palladium(II)[53]; XIKZON: Dichlorido[bis(2-hexylsulfanyl)-1H-benzimidazole-κN 3 ]palladium(II)[54]; ZIWTEH: trans-Dichlorido-bis(1H-benzimidazole)-palladium(II)[55].…”

mentioning

confidence: 99%

See 1 more Smart Citation

Synthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis

et al. 2021

View full text Add to dashboard Cite

The aim of the work was to synthesize new perspective compounds of palladium and platinum with nitrogenous bases (guanine), promising for use in biomedicine and catalysis. The article describes the synthesis of new [PdCl2(HGua)2]Cl2·H2O and [PtCl5(HGua)]·2H2O compounds using wet chemistry methods. The structure of the obtained single crystals was established by the method of single crystal X-ray diffraction. The complexes have an M-N bond, and the organic ligand is included in the first coordination sphere. The analysis of Hirshfeld surfaces for the obtained complexes and their analogues for the analysis of intermolecular interactions was carried out. In the palladium complex we obtained, π-halogen and π-stacking interactions were found; in analogues, such interactions were not found. π-halogen and halogen interactions were found in structure of platinum complex and its analogues.

show abstract

Corrosion self-diagnosing and self-repairing polymeric coatings based on zeolitic imidazolate framework decorated hydroxyapatite nanocontainer on steel

Liu

Cheng

Cui

et al. 2022

Chemical Engineering Journal

View full text Add to dashboard Cite

Synthesis, crystal structures and biological activities of palladium(II) complexes of benzimidazole and 2-methylbenzimidazole

Cited by 17 publications

References 44 publications

Suzuki-Miyaura Çapraz Eşleşme Reaksiyonunda Katalizör Olarak Heterosiklik Bileşiklerin Uygulanması

Suzuki-Miyaura Çapraz Eşleşme Reaksiyonunda Katalizör Olarak Heterosiklik Bileşiklerin Uygulanması

Synthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis

Corrosion self-diagnosing and self-repairing polymeric coatings based on zeolitic imidazolate framework decorated hydroxyapatite nanocontainer on steel

Contact Info

Product

Resources

About