Synthesis of a novel mono-component intumescent flame retardant and its high efficiency for flame retardant polyethylene

Xia, Siyu; Zhang, Zhiyong; Leng, Yang; Li, Bin; Xu, Min

doi:10.1016/j.jaap.2018.08.017

Cited by 51 publications

(29 citation statements)

References 33 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The pyrolysis behavior of PPMPNG, pure UPR, and UPR‐15 (FR‐UPR) thermosets was investigated by Py‐GCMS analysis. According to our previous work, the pyrolysis products of PPMPNG mainly included vinylidene (1), 1,3‐butadiene (2), piperazine derivative (3, 4), and methylphosphonic acid derivative (5, 6), as shown in Table . Some pyrolysis products such as vinylidene (1), 1,3‐butadiene (2), and piperazine and its derivative (3, 4) could occur cross‐linking and charring.…”

Section: Resultsmentioning

confidence: 99%

“…The flame retardant PPMPNG was synthesized from methylphosphonic acid, piperazine, and neopentyl glycol according to the reported literature . The chemical structure of PPMPNG was illustrated in Scheme .…”

Section: Methodsmentioning

confidence: 99%

“…It was a promising approach to further improve the flame retardant efficiency by strengthening the flame retardant effect of IFR in gaseous phase. According to our previous research work, the compound containing methylphosphonic acid unit exhibited the quenching effect for active free radicals and then interrupted the combustion chain reaction in the gas phase during combustion . It would be an alternative approach for enhancing the flame retardant properties of UPR materials by using the mono‐component IFR containing methylphosphonic acid groups.…”

Section: Introductionmentioning

confidence: 99%

“…The ingredients of IFR existing in a single-molecule can interact with each other more closely and quickly, and then exhibit much better synergistic effect. [21][22][23] Gao et al 19 24 the compound containing methylphosphonic acid unit exhibited the quenching effect for active free radicals and then interrupted the combustion chain reaction in the gas phase during combustion. 25 It would be an alternative approach for enhancing the flame retardant properties of UPR materials by using the mono-component IFR containing methylphosphonic acid groups.…”

mentioning

confidence: 99%

See 3 more Smart Citations

Preparation of highly efficient flame retardant unsaturated polyester resin by exerting the fire resistant effect in gaseous and condensed phase simultaneously

Jie

Zhang

et al. 2019

Polymers for Advanced Techs

Self Cite

View full text Add to dashboard Cite

The unsaturated polyester resins (UPR) were usually applied in electronic equipment, but the intrinsic flammability severely retrained their application. A mono‐component flame retardant poly (piperazine methylphosphonic acid neopentylglycol ester) (PPMPNG) made in our lab was selected and applied to improve their flame retardant performance. The UPR thermosets achieved UL‐94 V‐0 grade during vertical burning tests and the limiting oxygen index was as high as 32.1% when 15 wt% PPMPNG was incorporated. PPMPNG promoted the decomposition and carbonization of UPR materials in advance during heating process, and the residual mass was effectively enhanced at high temperature. The flame retardant mechanism of UPR/PPMPNG thermosets was investigated by pyrolysis‐gas chromatography/mass spectrometry tests, and the measurement of the morphologies and chemical components of the char residue. The phosphine oxygen radical was generated and then quenched the active free radicals in gas phase. Moreover, the av‐EHC of FR‐UPR was declined from 15.8 MJ kg−1 of pure UPR to 8 9 MJ kg−1 corresponding a reduction of 43.6%, which also verified the flame retardant effect in gas phase. The compact, integrated, and graphitized char layer was produced on materials surface and then exerted excellent barrier effect in condensed phase. Thus, the UPR/PPMPNG composites were conferred superior flame retardant properties.

show abstract

Section: Resultsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

mentioning

confidence: 99%

See 2 more Smart Citations

Preparation of highly efficient flame retardant unsaturated polyester resin by exerting the fire resistant effect in gaseous and condensed phase simultaneously

Jie

Zhang

et al. 2019

Polymers for Advanced Techs

Self Cite

View full text Add to dashboard Cite

show abstract

“…Gao et al synthesized amino trimethylene phosphonic acid melamine salt (MATMP) as mono‐component intumescent flame retardant to improve the water resistance and thermal stability of intumescent flame‐retarded polypropylene (PP). Xia et al prepared a novel mono‐component intumescent flame retardant named piperazine methylphosphonic acid neopentylglycol ester (PPMPNG) to improve the char yield and thermal stability of polyethylene. Abdelkhalik et al synthesized a novel mono‐component intumescent flame retardant named melamine salt of pentaerythritol phosphate kaolin (MPPK) and then applied in PP to obtain satisfactory flame retardancy and thermal stability.…”

Section: Introductionmentioning

confidence: 99%

Synergistic effect of bismuth oxide and mono‐component intumescent flame retardant on the flammability and smoke suppression properties of epoxy resins

Jia

Yan

et al. 2019

Polymers for Advanced Techs

View full text Add to dashboard Cite

A novel mono‐component intumescent flame retardant named pentaerythritol phosphate melamine salt (PPMS)‐hybrid bismuth oxide (PPMS‐Bi2O3) was synthesized and carefully characterized by FTIR, 1H NMR, 31P NMR, SEM‐EDS, and TG analyses. Then, PPMS‐Bi2O3 was utilized as flame retardant for epoxy resins (EPs), and the thermal stability, flame retardancy, and smoke suppression properties of EP composites were investigated. TG results show that PPMS‐Bi2O3 is more conducive to enhance the thermal stability and char forming ability of EP composites compared with the same addition of PPMS or the mixture of PPMS and Bi2O3, and this positive effect is enhanced with the increasing Bi2O3 content. Cone calorimeter test reveals that the PPMS‐Bi2O3 can effectively reduce the heat release and smoke production in comparison with PPMS or the mixture of PPMS and Bi2O3 due to the formation of a more compact and intumescent char against fire, as judged by digital photographs and SEM images. EDS analysis indicates that the combination PPMS and Bi2O3 by hydrogen bonds promotes to generate more phosphorus‐rich and aromatization structures in the condensed phase that enhance the barrier effect and anti‐oxidation ability of the char, thus imparting higher flame retardant and smoke suppression efficiencies to EP composites.

show abstract

Multicomponent Flame Retardants

Schartel¹

2021

Non‐Halogenated Flame Retardant Handbook 2 Nd Edition

View full text Add to dashboard Cite

Synthesis of a novel mono-component intumescent flame retardant and its high efficiency for flame retardant polyethylene

Cited by 51 publications

References 33 publications

Preparation of highly efficient flame retardant unsaturated polyester resin by exerting the fire resistant effect in gaseous and condensed phase simultaneously

Preparation of highly efficient flame retardant unsaturated polyester resin by exerting the fire resistant effect in gaseous and condensed phase simultaneously

Synergistic effect of bismuth oxide and mono‐component intumescent flame retardant on the flammability and smoke suppression properties of epoxy resins

Multicomponent Flame Retardants

Contact Info

Product

Resources

About