Synthesis of magnetic ferrogels: a tool-box approach for finely tuned magnetic- and temperature-dependent properties

Abstract

Multi responsive hydrogels have many potential applications in the field of medicine as well as technical fields and are of great interest in fundamental research. Here we present the synthesis and characterization of tailored magnetic hydrogels – micro- as well as macrogels – which consist of iron oxide and cobalt ferrite, varying in phase and morphology, embedded in a thermoresponsive polymer. We introduce new ways to synthesize magnetic particles and revisit some common strategies when dealing with particle synthesis. Subsequently we discuss the details of the thermoresponsive matrix and how we can influence and manipulate the thermoresponsive properties, i.e. the lower critical solution temperature. Ultimately, we present the particle-hydrogel composite and show two exemplary applications for particle matrix interactions, i.e. heat transfer and reorientation of the particles in a magnetic field.