Synthesis of nitrogen-rich B–C–N materials from melamine and boron trichloride

Popov, C.; Saito, Kimitsugu; Yamamoto, Kazuhiro; Ouchi, Akihiko; Nakamura, Takako; Ohana, Yoritsugu; Koga, Yoshinori

doi:10.1023/a:1004394129980

Cited by 23 publications

(14 citation statements)

References 17 publications

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“…This atomic ordering is inconsistent with the cohesive energy calculations where isomers with BN and CC fragments are preferred over those with direct CN and BC bonds. However, evidence of significant BC and CN bonds in BC 2 N materials has been reported experimentally. ,, Kawaguchi et al suggested that B−C−C−N and B−N together are the basic building block from which the structure of BCN graphite-like materials can be generated by repetition. It is interesting to note that in the triatomic BCN molecule, BNC ( 1 Σ + ) is the global minimum followed by the BCN 1 Σ + state by 10 kcal/mol .…”

Section: Resultsmentioning

confidence: 99%

Structure, Stability, and Bonding of BC₂N: An ab Initio Study

1998

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Tetra-atomic BC2N, the building block of the mixed carbon and BN clusters, has been studied at the HF, MP2, and CCSD(T) levels using both double- and triple-ζ basis sets with polarization and diffuse functions. In contrast to the parents C4 and (BN)2, the linear triplet (3Π) BCCN is found to be the most stable and the linear−cyclic energy difference is about 28 kcal/mol. In the cyclic structure, isomers with adjacent B and N atoms are more stable, whereas no general trend of atomic combination has been found in the linear isomers. The preferred sequence of atoms in the linear form depends on the cluster size. The nature of bonding and atomization energies of the parent and hybrid molecules are compared and discussed.

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Section: Resultsmentioning

confidence: 99%

Structure, Stability, and Bonding of BC₂N: An ab Initio Study

1998

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“…Although melamine has been frequently used as a strong nitrifying agent in synthesizing nitride 28 – 30 or carbonitride 31 , 32 compounds, heat treatment at relatively high temperatures for a given duration was often used to complete the reaction. In most of these studies, melamine reacts directly with metal oxides or elemental metals to form the nitride products.…”

Section: Introductionmentioning

confidence: 99%

A novel, simple and rapid route to the synthesis of boron cabonitride nanosheets: combustive gaseous unfolding

Jalaly

Gotor

Semnan

et al. 2017

Sci Rep

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The ternary compound boron carbonitride (BCN) was synthesized in the form of few-layer nanosheets through a mechanically induced self-sustaining reaction (MSR). Magnesium was used to reduce boron trioxide in the presence of melamine in a combustive manner. The process to form the nanostructured material was very rapid (less than 40 min). The prepared powder was investigated by various techniques such as X-ray diffraction (XRD), Fourier Transform infrared (FTIR), Micro-Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy (HRTEM), and electron energy loss spectroscopy (EELS). The thermal stability and the optical behavior of the BCN nanosheets were also studied by thermal analysis and UV-vis spectroscopy, respectively. The formation mechanism of the nanosheet morphology was described in detail.

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“…This approach was exclusively used in thermal CVD. 121,139,352 It could be due to the fact that the focus of PACVD in the B-C-N system was strongly driven by the c-BN/diamond pair.…”

Section: Use Of C-n-containing Co-reagent With B Precursorsmentioning

confidence: 99%

Chemical vapour deposition of sp2-hybridised B-C-N materials from organoborons

Souqui

2019

Linköping Studies in Science and Technology. Dissertations

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Up left: top view scanning electron micrograph (SEM) of sp 2 -BN grains and 3C-SiC grains on Si(111). Up right: top view SEM of r-BN grains on ZrB2, surrounded by a-BN. Bottom left: top view SEM of the surface of a 1.5 µm thick r-BN film deposited from TMB covered with a-BN. Bottom right: top view SEM of rhombohedral boron carbide grains on silicon carbide. Back side:Up: cross section SEM of DRAM structures of aspect ratio 60:1 (low magnification) and a-BxC film deep in the trenches (high magnification).Bottom, from left to right: top view SEM of sp 2 -BCxNy nanowalls deposited from plasma CVD, with increasing degree of disorder and complexity.During the course of research underlying this thesis, Laurent Souqui was enrolled in Agora Materiae, a multidisciplinary doctoral program at Linköping University, Sweden.

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Synthesis of nitrogen-rich B–C–N materials from melamine and boron trichloride

Cited by 23 publications

References 17 publications

Structure, Stability, and Bonding of BC₂N: An ab Initio Study

Structure, Stability, and Bonding of BC₂N: An ab Initio Study

A novel, simple and rapid route to the synthesis of boron cabonitride nanosheets: combustive gaseous unfolding

Chemical vapour deposition of sp2-hybridised B-C-N materials from organoborons

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Synthesis of nitrogen-rich B–C–N materials from melamine and boron trichloride

Cited by 23 publications

References 17 publications

Structure, Stability, and Bonding of BC2N: An ab Initio Study

Structure, Stability, and Bonding of BC2N: An ab Initio Study

A novel, simple and rapid route to the synthesis of boron cabonitride nanosheets: combustive gaseous unfolding

Chemical vapour deposition of sp2-hybridised B-C-N materials from organoborons

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Structure, Stability, and Bonding of BC₂N: An ab Initio Study

Structure, Stability, and Bonding of BC₂N: An ab Initio Study