Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10]6− units

Synthesis and Characterization of a Novel Nonlinear Optical Material Mg2Na2ZnB4O10

“…The 1030 cm -1 band are likely the asymmetric and symmetric stretching of B-O in BO 4 . The deformation vibration at 918 and 687 cm -1 can be assigned as the bending of BO 3 groups [19,[23][24][25][26][27][28]. …”

“…In the inorganic family crystals, borate crystals have attracted much attention due to their intrinsic favorable properties. The borate based NLO crystals like lithium borate LiB 3 O 5 (LBO) [10], -Ba 2 B 2 O 4 (BBO) [11], CsLiB 5 O 10 (CLBO) [12], SrBe 2 B 2 O 7 (SBBO) [13], KBe 2 BO 3 F 2 (KBBF) [14], K 2 Al 2 B 2 O 7 (KAB) [15], Re 2 CaB 10 O 19 (ReCB) [16], K 3 YB 6 O 12 (KYB) [17], La 2 CaB 10 O 19 (LCB) [18], and Li 2 Pb 2 CuB 4 O 10 [19] have excellent transmission properties in combination with NLO behavior. Therefore, intense work has begun in developing new materials for NLO applications and expanding the frequency range provided by the conventional laser sources [4,20].…”

Cation effect investigation on electronic structure, magnetic and optical properties of Li2Pb2CuB4O10

“…To advance the role of cations, we will investigate a lithium-lead-copper-containing material Li 2 Pb 2 CuB 4 O 10 [14]. Li 2 Pb 2 CuB 4 O 10 was synthesized first by Li et al to the best of our knowledge, there is no report about the electronic structure and magnetic properties.…”