Synthesis TiO₂ using sonochemical method and responses the CO₂ gas of the nanoparticle TiO₂ layers on the QCM sensor surfaces

Abstract

TiO2 synthesis using sonochemical methods and their coating on the surface of the Quartz Crystal Microbalance (QCM) sensor utilizing the spin coating method has been carried out. The synthesis started by mixing 7 ml of titanium (IV) isopropoxide (TTIP) (97%) in 70 ml of ethanol (96%). The mixture of TTIP solution was stirred for 30 minutes. After ward, the sonication was carried out for 4 hours at a frequency of 40 kHz and heated for 16 hours at 80 °C. To produce TiO2 powder, the precursor was calcined at 500°C for 3 hours. The TiO2 nanoparticle was analyzed using XRD, and the particle size was observed using SEM/Eds. Based on the XRD results, the crystal structure of Anatases was obtained at the 2θ (deg) of 25.503°(101), 29.56° (103), 36.20° (004), 37.977° (112), 48. 25.9° (200), 54.100° (105), 55.272° (211), 62.89°. The particle size from the SEM results showed the average particle size in the range of ±7μm-±54 nm with the majority in ±96 nm. The obtained TiO2 was dissolved with ethanol then the solvent was deposited on the QCM surface using the spin coating method. A homogeneous and porous surface structure is obtained from the SEM observation. The coated QCM was tested for its ability to adsorb CO2 gas. QCM was exposed to CO2 gas for 100 seconds with a constant exposure discharge. A positive response was obtained for the adsorbability of the coated QCM to adsorb CO2 gas with time variations. TiO2’s response against CO2 gas adsorption indicates that TiO2 can be further investigated as a CO2 gas sensor. The measuring response of the TiO2 layer on the QCM sensor was conducted to adsorb CO2 gas.

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Synthesis and Characterization of TiO2-Chitosan Beads and Its Application as A Degradation Agent of Methylene Blue

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