Synthetic and mechanistic investigations on manganese corrole-catalyzed oxidation of sulfides with iodobenzene diacetate

Manganese corrole catalyzed selective oxidation of styrene to benzaldehyde: sodium nitrite functions as an oxidant and cocatalyst

“…5 The manganese corrole has also been successfully applied in the catalytic hydroxylation of cyclohexene 6 and oxidation of sulfides. 7 In manganese corrole catalyzed oxidation reactions, PhIO, TBHP, PhI(OAc) 2 , KHSO 5 and m -CPBA are usually used as oxidants. The cleanest oxidant is O 2 or H 2 O 2 .…”

Reacting Molecular Oxygen with Butanone under Visible Light Irradiation: A General Aerobic Oxidation of Alkenes, Sulfides, Phosphines, and Silanes

“…Heteroatomic compounds such as thioether, , phosphine, , and silane , are important in synthetic chemistry, pharmaceuticals, agrochemicals, and polymers. The effectiveness of our methodology in heteroatom oxidation was also demonstrated, as shown in Scheme .…”