Temperature dependence of the rate constant for hydrogen atom reaction with Cl 2 −• in water by pulse radiolysis of aqueous HCl solution

Reaction of the hydrogen atom with nitrous oxide in aqueous solution – pulse radiolysis and theoretical study

“…In this system the hydroxyl radical is rapidly converted to Cl 2 c À . 18 Comparative measurements have been also carried out for N 2 -saturated solutions. The decay of Cl 2 c À absorbance was traced over the temperature range of 296-346 K at 340 nm being the absorption maximum of Cl 2 c À .…”

Rate constants of dichloride radical anion reactions with molecules of environmental interest in aqueous solution: a review

“…. Manifold reactions proceed in such a system (Buxton et al 1988a, b;Brigante et al 2014;Szala-Bilnik et al 2014;Kazmierczak et al 2015Kazmierczak et al , 2019).…”

“…•may disappear from the solution in disproportionation reaction (Kazmierczak et al 2015(Kazmierczak et al , 2019:…”

“…The pH is adjusted to the acidic range (pH 1–4) to ensure the efficient formation of Cl 2 •- . Manifold reactions proceed in such a system (Buxton et al 1988a , b ; Brigante et al 2014 ; Szala-Bilnik et al 2014 ; Kazmierczak et al 2015 , 2019 ).…”

“…+ k 6 [S]. In purified water, in the absence of suitable reactants, Cl 2 •- may disappear from the solution in disproportionation reaction (Kazmierczak et al 2015 , 2019 ):…”