“…Aquitards consist of fine sediments such as clay and silt in the low‐energy depositional environments, and they are natural hydrogeological barriers and protect regional aquifers from contamination (Neuzil, ; Yan, Kerrich, & Hendry, ; Zhuang, Zhou, Zhan, & Wang, ). Aquitards are distributed over large land areas across the globe, covering the entire basins or alluvial plains, and sometimes even extending under the sea, such as the Dakota aquifer system in the United States and the Yangtze Delta in China (Cihan, Zhou, & Birkholzer, ; Guo & Li, ; Guo, Li, Zhou, & Huang, ; Konikow & Neuzil, ; Zhou, Guo, & Dou, ). Once the contaminants enter into an aquitard, they cannot be easily extracted due to its high porosity and low permeability and the binding force between the contaminant ions and the negatively charged clay surface (Barbour, Hendry, & Wassenaar, ; Hendry, Barbour, Boldt‐Leppin, & Wassenaar, ).…”