In this article, the Surlyn V R 8920 and AX 8900 were mixed as hybrid nucleating agents for glass fiber (GF)reinforced polyethylene terephthalate (PET)/polybutylene terephthalate (PBT) alloy. The crystallization behaviors on GF-reinforced PET/PBT alloy with compound nucleating agents of Surlyn V R 8920 and AX 8900 were studied by differential scanning calorimeter. The Jeziorny method, Mo method, and Kissinger method were used for studying the non-isothermal crystallization process of the composite alloys. While single AX 8900 cannot further improve the crystallization properties of the alloy and reduced the crystallization rate, the introduction of Surlyn V R 8920 can effectively ameliorate the condition. The results demonstrated the hybrid nucleating agents of Surlyn V R 8920 and AX 8900 not only can accelerate crystal growth, but also can significantly reduce the energy barrier, and it has a good effect in the alloy to the nucleation. POLYM. COMPOS.,