The Cadmium-Cadmium Halide Systems¹

Mixtures of Metals With Molten Salts

“…*the iodide system,80 however, seems t o be i n e r r o r , compared with 10 mole 5, according t o Topol and Landis. 79 The l a t t e r determination i s not com- CdC12. A n a l t e r n a t i v e explanation i s t h a t i n small concentrations t h e complex anion may a c t a s a "common ion" with respect t o some of t h e ions of t h e solvent s a l t , CdC12, or, i n other words, t h a t a c e r t a i n concentrat i o n of complex anions such a s (cdc14)" i s present, even i n pure molten CdC12.…”

Electrical Conductivities of Molten Bi–BiI3 Solutions

“…21 On the other hand, evidence that bismuth dissolves in BiI3 to form BiI in the salt-rich melt is given by cryoscopic-9 and magnetic-susceptibility23 studies. For example, in the case of the Bi-BiCIa system, it has been shown by emf measurements 18 that the monomer, BiCl, is predominant only in the very dilute solutions «0.5 mole % Bi) at temperatures below 300°C.…”

Studies on the Solution of Cadmium in Molten Cadmium Chloride. II. Effects of Added Chlorides on the Solubility of Cadmium in Molten Chloride

“…The results in our preceding reports 3) ,4) showed that in a dilute solution of cadmium in cadmium chloride, cadmium exists as Cd/+ ion and that this subnormal ion is stable even when potassium chloride or aluminum chloride is added. However, Topol et al 6 K' == N Cd}+ / N Cd2+ (8) where N Cd 2+ and N Cd 2+ are cation frac- The reaction shifts to the left by the addition of the salt with a higher potassmm chloride ratio (i.e. decreasing a), and to the right by a higher aluminum chloride (i.e.…”