The Covalent Hydrides and Hydrides of the Groups V to VIII Transition Metals

Electrophilic Addition vs Electron Transfer for the Interaction of Ag+ with Molybdenum(II) Hydrides. 2. Reaction with CpMoH(CO)2(PMe3)

“…Another possibility, however, could involve the substitution of “AgH” by MeCN. Silver hydride , is unstable and thermodynamically disfavored relative to the elements. − In this respect, reaction 3 would be analogous to the elimination of H 2 upon protonation of 1 in MeCN, to form the same final product 3 . The two possibilities are highlighted in Scheme .…”

Feasibility Study of Supercritical Light Water Cooled Fast Reactors for Actinide Burning and Electric Power Production, 3rd Quarterly Report

“…The three main constituents of Alloy 718 (i.e., nickel, chromium, and iron) do not form stable hydrides at the hydrogen pressures and temperatures of interest to our application [Siegel and Libowitz 1968]. Therefore, massive hydriding of the moderator box is not a concern.…”

Complex Hydride Compounds with Enhanced Hydrogen Storage Capacity

“…From the most illuminating references [Refs. 29,30,31,32,33,34,35], we surveyed common structure-property observations and rules for their stable existence that were derived from complex hydride crystallographic, spectroscopic, and thermochemical characterizations, as summarized in Table 4. These observations include: the structural correlation of certain complex hydride stoichiometries to specific ternary halide or oxide compounds with analogous stoichiometries, typical bond distances within various types of hydride complexes, and geometrical relationships for interactions between neighboring metallic cations and between neighboring hydrogen atoms.…”