The Effects of Exposed Specific Facets and Sulfation on the Surface Acidity of Cu₂O Solids

Abstract

Cuprous oxide microcrystals with {111}, {111}/{100}, and {100} exposed facets were synthesized. 31P MAS NMR using trimethylphosphine as the probe molecule was employed to study the acidic properties of samples. It was found that the total acidic density of samples increases evidently after sulfation compared with the pristine cuprous oxide microcrystals. During sulfation, new {100} facets are formed at the expense of {111} facets and lead to the generation of two Lewis acid sites due to the different binding states of SO42− on {111} and {100} facets. Moreover, DFT calculation was used to illustrate the binding models of SO42− on {111} and {100} facets. Also, a Pechmann condensation reaction was applied to study the acidic catalytic activity of these samples. It was found that the sulfated {111} facet has better activity due to its higher Lewis acid density compared with the sulfated {100} facet.