The influence of rf power and oxygen flow rate during deposition on the optical transmittance of copper oxide thin films prepared by reactive magnetron sputtering

Abstract

Copper oxide films have been sputter deposited on glass substrates by reactive rf magnetron sputtering, using a solid copper target and an argon–oxygen gas atmosphere. The films were characterized by SEM/EDAX, XPS, AFM, profilometry and spectrophotometry. Optical transmission in the prepared films was measured by spectrophotometry in the 400–850 nm wavelength region. The optical transmission was found to increase from below 10% to above 80% as the rf power was reduced from 800 to 200 W at a wavelength of 550 nm. The optical bandgap value also increased from 2.05 to 2.4 eV with a reduction in rf power from 800 to 200 W. This bandgap change indicates the possibility of selectively depositing an optically transparent Cu2O-rich film, an absorbing black CuO-rich film or a mixture of both phases by varying the rf power during deposition. The oxygen flow rate during deposition had a less significant effect on the optical transmittance and bandgap of the films. This dependence of the stoichiometry of the copper oxide films on the deposition conditions is explained in terms of the sticking coefficient, nucleation rates and migration of impinging copper and oxygen species on the substrate. This information is expected to underlie the successful development of copper oxide films for technological applications requiring controlled optical transmission in the visible.

Fabrication of cuprous and cupric oxide thin films by heat treatment

“…The Cu 2 O and CuO are p-type semiconductors with bandgaps in the range of 1.8-2.5 eV and 1.21-2.00 eV [1,2], respectively. Copper oxide thin films have wide range of applications in energy harvesting and storage such as, solar cells [2][3][4][5], photo-electro-chemical cells (PECs) [6,7], photocatalysts [8,9], and lithium ion batteries [10].…”

Annealing Temperature Dependence on the Physicochemical Properties of Copper Oxide Thin Films

“…power and oxygen flow rate on Cu oxide thin films prepared by reactive magnetron sputtering was studied by Ogwu et al. 21 However in our knowledge, annealing effect on the Cu oxide thin films during deposition by r.f. sputtering is rare.…”

Molecular Precursor Method for Fabricating p-Type Cu2O and Metallic Cu Thin Films

“…Over the past years, the quest to obtain high-quality Cu 2 O ilms has fueled the development of many physical processing techniques including sputering, thermal oxidation, vacuum evaporation, molecular beam epitaxy, and electrodeposition. However, reproducible formation of Cu 2 O ilms uncontaminated by the CuO phase is a formidable challenge from the technical perspective [29,30]. In addition, most of the aforementioned physical processing techniques are not economically viable in large area applications.…”