The effects of plasma enhanced atomic layer deposition (PEALD)-AlN interfacial passivation layer (IPL) on the Al 2 O 3 /In 0.53 Ga 0.47 As interfaces qualities are studied with different plasma powers. The improvement in electrical properties, including capacitance-voltage (C-V ) hysteresis, frequency dispersion, and interface state densities ( D it ) are demonstrated on the Al 2 O 3 /n, p-In 0.53 Ga 0.47 As MOS capacitors. The excellent C-V behaviors are observed on both type of In 0.53 Ga 0.47 Asbased MOS devices by performing a thin AlN-IPL at the plasma power of 150 W. To explore the interaction between PEALD-AlN layer and In 0.53 Ga 0.47 As surface, X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy analyses have also been characterized. Index Terms-Al 2 O 3 , AlN, In 0.53 Ga 0.47 As, MOS capacitor (MOSCAP), plasma enhanced atomic layer deposition (PEALD).