Abstract. Two odd-odd nuclei from the A ∼ 100 and A ∼ 130 regions, namely 102 Rh and 134 Pr have been studied in search for chiral doublet bands via 94 Zr( 11 B,3n) 102 Rh and 119 Sn( 19 F,4n) 134 Pr reactions, respectively. Two nearly degenerate bands built on the πg 9/2 ⊗ νh 11/2 configuration have been identified in 102 Rh and on the πg 11/2 ⊗ νh 11/2 configuration for 134 Pr. Lifetimes of excited nuclear states were measured using Dopplershift attenuation method and recoil distance Doppler-shift method. The deexciting gamma rays were registered by the Indian National Gamma Array for 102 Rh and using the EUROBALL IV detector array with an inner Bismuth Germanate (BGO) ball for 134 Pr, respectively. Polarization and angular correlation measurements have been performed to establish the spin and parity assignments for these bands. The derived reduced transition probabilities are compared to the predicitons of the two quasiparticles + triaxial rotor and interacting boson fermion-fermion models.