The Mechanochemical Reaction of Palladium(II) Chloride with a Bidentate Phosphine

Evaluating Feedstocks, Processes, and Products in the Teaching Laboratory: A Framework for Students To Use Metrics to Design Greener Chemistry Experiments

“…Transitioning to more benign or recyclable solvents can therefore potentially yield significant benefits from a sustainability standpoint. Mechanochemical milling − and other neat techniques for alcohol oxidations, , Claisen condensations, amine reductions, Cannizzaro, , Wittig, , Baeyer-Villager and Ullman reactions have been adapted to teaching laboratories in order to demonstrate the possibility of removing solvents from organic transformations. If a solvent is indeed necessary for a particular transformation, popular clean solvents such as water, ionic liquids, or CO 2 have become quite commonplace in the chemical education community. ,,− …”

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Eco-Friendly Physical Activation Methods for Suzuki–Miyaura Reactions

“…An example of environmentally friendly preparation of PdCl 2 with a bidentate 1,5-bis(diphenylphosphino)-pentane has been described in the Journal of Chemical Education; this procedure consists of grinding a mixed powder against the side of a 50 mL round-bottomed flask so to achieve high metal loading and high particle dispersion capacities [150]. Many other supports with high pore volume have been used, such as mesoporous silica, carbon and one reported example of Pd dispersed in ascorbic acid.…”

Tunable transport and optoelectronic properties of monolayer black phosphorus by grafting PdCl2quantum dots

“…45 In general, the Pd atom is a typical transition metal for coordinating P and Cl ligands. [46][47][48] These complexes have shown wide spread applications in electronics, photoelectrochemistry, and electrochemistry. [49][50][51] Usually, Pd has a 4d 10 conguration and preferentially provides a dsp 2 hybrid environment to coordinate with four ligands, i.e., forms a planar quadridentate complex.…”