Spatial ordering has been observed recently during various photochemical reactions. Convoluted concentration bands first appear near the surface of shallow irradiated solutions. They thereafter extend into the bulk, and finger-like structures spontaneously develop. We discuss here the possible role of double-diffusion effects in the onset of this phenomenon. Indeed, chemical reactions occurring near the surface or evaporation of the solvent, or both, induce in the bulk adverse gradients of a pair of properties (concentrations of solute or concentration and tem- (10)(11)(12).For the sake of clarity, we consider the following model.
IaXy2'The main problem is concerned with the determination of the time of onset for the instability to occur in the presence of the time developing gradients aAA(z,t) and adBO(z,t). A simple method to estimate this time is provided by the quasistationary approximation. It consists in freezing the concentration profile at a given time and determining its stability. Although this approximation is known to yield inaccurate values of the growth rate of the disturbances, it seems in fact to predict the time at which the structuration first develops in the layer accurately (13).As the concentration gradients are slowly developing in time (DAB 10-5 cm2s-1), their effects can only be felt in a small layer at the top of the solution, the thickness of which is of the order of (DAt)'12 (10-2 after 10 s). An The publication costs of this article were defrayed in part by page charge payment. This article must therefore be hereby marked "advertisement" in accordance with 18 U.S.C. §1734 solely to indicate this fact.