The organo-pillared porous magnetic framework Co4(SO4)(OH)6(H2NC2H4NH2)0.5·3H2O

Structural and Magnetic Modulation of a Purely Organic Open Framework by Selective Guest Inclusion

“…[1a, 4] Indeed, the puzzled construction of metal-organic open frameworks allows the exploration of novel structural/dynamic characteristics, as well as physical functions, such as, chirality, [5] electrical, [6] optical, [7] or magnetic. [8,[10][11][12][13][14][15] Among them, attainment of functional magnetic and/or dynamic structural porous solids is attracting considerable effort worldwide. [8,9] Magnetic porous solids have the potential to produce low-density magnetic materials or to develop multifunctional materials thanks to their capacity to encapsulate other functional molecular systems possessing additional conducting, optical, chiral, or nonlinear optical (NLO) properties.…”

“…[8,9] Magnetic porous solids have the potential to produce low-density magnetic materials or to develop multifunctional materials thanks to their capacity to encapsulate other functional molecular systems possessing additional conducting, optical, chiral, or nonlinear optical (NLO) properties. Thus far, ferromagnetic, [10] antiferromagnetic, [11] spin-frustration, [12] spincrossover, [13] metamagnetic, [14] or ferromagnetic [15] behavior have been introduced in porous structures. On the other hand, coordination polymers with dynamic pores open new Abstract: Solvent inclusion/evacuation caused variations in the structural and magnetic characteristics of the purely organic porous magnet based on the tricarboxylic-substituted PTMTC radical.…”

Synthesis, Crystal Structure, and Magnetic Properties of a Three‐Dimensional Hydroxide Sulfate: Mn5(OH)8SO4

“…[16][17][18][19][20] layered cobalt sulfates. [22,23] M. I. Khan et al reported a layered vanadium sulfate. [24] In most of the previous compounds prepared by hydrothermal techniques, the layers were like modified brucite, having some of the [MO 6 ] (M = octahedrally coordinated metal element) octahedra replaced by [TO 4 ] tetrahedra above and below the vacancies, whereas now a truly brucite-type magnetic layered compound has been reported by S. Vilminot et al [25] There are much fewer 3D compounds reported.…”

Self-assembly of a novel 3D copper(I)-tetrazolate supramolecular framework via interpenetration of porous 2D double-layer motifs

“…The aromatic face-to-face distances of 3.4655(7) and 3.6289(8) Å between the TAZ ligands from neighboring layers reveal p-p interactions, which help to stabilize this 3D interpenetrating supramolecular structure. Although several types of double-layered architectures have been obtained through the assembly of different building blocks [35][36][37][38], the porous doublewave-shaped network of 1 is rare [39]. In order to further analyze this net, we can define the [Cu 2 (TAZ) 2 ] binuclear motifs and l 3 -cyanide groups as nodes, and Cu(1), Cu(6) and l 2 -CN as linkers.…”