“…5a) for the samples from which nutrient concentrations are available, although it can be higher than this (unpublished data, Waldron; Dawson et al, 2004). Whilst each sample is a "snapshot" of DOC export and there may be considerable variation between samples depending on hydrological conditions (Grieve, 1994), this seasonal pattern of changing concentrations is observed elsewhere (e.g., Billett et al, 2004;Worrall et al, 2006), with highest concentrations in catchment outflow at the end of summer, after peak terrestrial productivity and strongly influenced by increased hydrological export (Tipping et al, 2007). Early summer 2007 was particularly wet in the UK (Fig.…”