1970
DOI: 10.1007/bf02044889
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Thermal decomposition mechanism of ammonium perchlorate

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Cited by 5 publications
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“…Similar values of activation energies of thermal decomposition and sublimation [54], identical composition of the products of decomposition [55] and sublimation [56], inhibition of the reaction in ammonia vapour [55] and acceleration in the vapour of perchloric acid [57,58], favour proton transfer mechanism. A scheme of thermal decomposition of AP proposed by Jacobs [54] can be presented as a version of proton mechanism [17]: Step I involves a pair of ions in perchlorate ammonium lattice.…”
Section: Proton Transfer Mechanismmentioning
confidence: 99%
“…Similar values of activation energies of thermal decomposition and sublimation [54], identical composition of the products of decomposition [55] and sublimation [56], inhibition of the reaction in ammonia vapour [55] and acceleration in the vapour of perchloric acid [57,58], favour proton transfer mechanism. A scheme of thermal decomposition of AP proposed by Jacobs [54] can be presented as a version of proton mechanism [17]: Step I involves a pair of ions in perchlorate ammonium lattice.…”
Section: Proton Transfer Mechanismmentioning
confidence: 99%