Thermo- and oxidation-sensitive poly(meth)acrylates based on alkyl sulfoxides: dual-responsive homopolymers from one functional group

Abstract

Alkyl sulfoxide side groups introduce thermo- and oxidation-sensitivity into poly(meth)acrylates, thus realizing new dual-responsive homopolymers based on one functional group.

Effect of Cationic Groups on the Selectivity of Ternary Antimicrobial Polymers

“…The protected cationic monomers tert ‐butyl (2‐acrylamidoethyl)carbamate (Boc‐AEAm) and N ‐isopentylacrylamide (Im) were synthesized according to the protocol reported in the previous study. [ 28 ] The protected cationic monomers 1,3‐di‐Boc‐guanidiethyl acrylamide (diBoc‐GEA) and 2‐(methylthio)ethyl acrylate (Sm) were synthesized by following the protocols that were described by Martin [ 40 ] and Işık, [ 41 ] respectively.…”

Polymers fromS-vinyl monomers: reactivities and properties

“…[133][134][135] However, it is known in the literature that the hydrophilicity is lower compared to the sulfoxide. 136,137 Researchers have furthermore been interested in the atomic refraction of the sulfone moiety, which is still considerably higher than for other common groups, although not as high as the corresponding sulfides. 3,138 However, their atomic dispersion is much lower than for sulfides, which renders sulfones particularly attractive to not only enhance refractive indices of corresponding materials, but also increase their Abbe number.…”

Trendbericht: Makromolekulare Chemie

“…Kombiniert mit der Möglichkeit, die Sulfoxide zu Sulfonen zu oxidieren, ergeben sich so neue doppelt stimuliresponsive Polymethacrylate. 17) Hartmann und Schelhaas untersuchten, ob hochsulfatierte synthetische Glycomimetika die Virusbindung verhindern. Die kurz-und langkettigen Glycopolymere wirken auch in vivo antiviral.…”