Thionylimide–transition metal complexes

Hartmann, G.; Hoppenheit, R.; Mews, Rüdiger

doi:10.1016/s0020-1693(00)81506-6

Cited by 17 publications

(5 citation statements)

References 9 publications

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“…25 In 2015 Schulz and co-workers invoked adduct formation with B(C6F5)3 to stabilise HNSO, which was formed in situ by protonation of K[NSO] with stearic acid (Scheme 2). 6 Transition-metal complexes of the HNSO ligand, characterised only by IR and NMR spectra, were reported earlier by Mews et al 26 In a biological environment S-nitrosothiols RSNO are important species for the storage and transport of nitric oxide with potential applications in the treatment of blood circulation problems (for a comprehensive discussion of the chemistry of RSNOs and HSNO, see ref. 9).…”

Section: K2[nsn] + 2ch3coohmentioning

confidence: 97%

Fundamental chemistry of binary S,N and ternary S,N,O anions: analogues of sulfur oxides and N,O anions

Chivers

Laitinen

2017

Chem. Soc. Rev.

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Binary S,N anions, e.g., NSN and SSNSS, and related ternary S,N,O anions such as the structural isomers NSO/SNO and SSNO are rarely mentioned in inorganic chemistry textbooks, despite the fact that their salts were synthesised and structurally characterised more than 30 years ago. These fundamentally important species and their conjugate acids, e.g. HNSO and HSNO, have been the focus of numerous investigations in recent years in view of their significance in disciplines as diverse as atmospheric chemistry and cell biology. This Tutorial Review provides a consolidated account of the fundamental chemistry including synthesis, spectroscopic characterisation, molecular and electronic structures, and properties of these intriguing species, and compares these aspects of their behaviour with those of isoelectronic sulfur oxides and N,O anions. A final section draws attention to the significance and applications of these simple S-N species in a broader context.

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Section: K2[nsn] + 2ch3coohmentioning

confidence: 97%

Fundamental chemistry of binary S,N and ternary S,N,O anions: analogues of sulfur oxides and N,O anions

Chivers

Laitinen

2017

Chem. Soc. Rev.

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“…Hints for this variety come from our earlier results on the reaction of NSF 3 and its derivatives with various acceptors [2,10]; the nitrogen in HNS(O)F 2 [18] and H 3 CNS(O)F 2 [19] is attacked by metal centers and Lewis acids, and (CH 3 ) 2 NSO 2 F forms oxygen bonded adducts with Lewis acids [20]. AsF 5 possibly abstracts the fluoride ion from (H 3 CN=) 2 S(F)N(CH 3 ) 2 [21].…”

Section: Resultsmentioning

confidence: 99%

Fluorothiazynes, 50 years old and still exciting: electrophilic attack at the thiazyl nitrogen of NSF2NS(O)F2

Mews

Borrmann

Hoppenheit

et al. 2004

Journal of Fluorine Chemistry

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“…Basierend auf IR‐Daten berichteten Mews et al. bereits über die N‐Koordination in einer Reihe von Thionylimid‐Übergangsmetallkomplexen des Typs [(CO) 5 M←N(H)SO][AsF 6 ] (M=Mn, Re) …”

Section: Methodsunclassified

Isolierung labiler NSO‐Pseudohalogen‐Spezies

et al. 2016

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Mithilfe eines neuen Syntheseweges gelang es,d as labile Thionylimid, H-NSO,zugenerieren und mit der sterisch anspruchsvollen Lewis-Säure B(C 6 F 5 ) 3 abzufangen und vollständig zu charakterisieren. Zum Vergleich wurdee ine Reihe von Me 3 Si-NSO-Addukten untersucht. Die Reaktion von Me 3 Si-NSO mit dem Silyliumion [Me 3 Si] + führte zum bis dato unbekannten Iminosulfoniumion [Me 3 Si-N=S-O-SiMe 3 ] + ,das in Form von Salzen schwach koordinierender Carborationen isoliert und vollständig charakterisiert werden konnte.

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Thionylimide–transition metal complexes

Cited by 17 publications

References 9 publications

Fundamental chemistry of binary S,N and ternary S,N,O anions: analogues of sulfur oxides and N,O anions

Fundamental chemistry of binary S,N and ternary S,N,O anions: analogues of sulfur oxides and N,O anions

Fluorothiazynes, 50 years old and still exciting: electrophilic attack at the thiazyl nitrogen of NSF2NS(O)F2

Isolierung labiler NSO‐Pseudohalogen‐Spezies

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