Three-dimensional carbon framework as a promising anode material for high performance sodium ion storage devices

Wang, Peiyu; Yang, Bingjun; Zhang, Guoheng; Zhang, Li; Jiao, Haiyan; Chen, Jiangtao; Yan, Xingbin

doi:10.1016/j.cej.2018.07.150

Cited by 55 publications

(18 citation statements)

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“…From the above results, the CNS anode exhibits the superior rate capability and long cycling life for sodium ion storage, it is a suitable candidate for the application as the anode in SIHCs. Therefore, the sodium alginate derived AC has been chosen as the capacitor‐type cathode and the preparation process of AC was followed the method reported in our previous work . Figure S6 displays the electrochemical behaviors of the AC cathode.…”

Section: Resultsmentioning

confidence: 99%

“…A high energy density of 135 Wh kg −1 can be achieved at a power density of 250 W kg −1 , and the device retains an energy density of 69 Wh kg −1 at an ultrahigh power output of 25 kW kg −1 . The energy/power densities of SIHCs are shown in Ragone plots (Figure c and d) and are superior to several representative materials‐based devices such as 3D framework carbon//3D framework activated carbon (3DFC//3DFAC), 3D carbon framework//sodium alginate derived AC (3DCF//SDAC), TiO 2 mesocage graphene nanocomposite//AC (MWTOG//AC), Nb 2 O 5 @carbon core‐shell nanoparticles/reduced graphene oxide//AC (Nb 2 O 5 @C/rGO‐50//AC), nanotube‐like hard carbon//activated polyaniline‐derived carbon (NTHC‐1150//APDC), WS 2 nanosheets//mesoporous hollow carbon spheres (WS 2 nanosheets//m‐HC) and TiO 2 @CNT@C nanorods//biomass‐derived activated carbon (TiO 2 @CNT@C// BAC) …”

Section: Resultsmentioning

confidence: 99%

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Carbon Nanosheet Anode for Sodium‐Ion Storage and Its Application in Sodium‐Ion Hybrid Capacitors

et al. 2020

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In this study, sodium ion hybrid capacitors (SIHCs) constructed by using battery-type carbon nanosheet (CNS) as anode and capacitive activated carbon (AC) as cathode are reported. The CNSs with large interlayer spacing were deposited on Na 2 CO 3 powder by using chemical vapor deposition method. The CNS anode for sodium ion storage exhibits outstanding rate capability (138 mAh g À 1 at 10 A g À 1 , 63 % retention of the capacity at 0.05 A g À 1 ) and excellent long-term cyclability at 10 A g À 1 after 12500 cycles. Benifting from high performance of anodes abovemensioned, the assembled SIHC based on CNS and AC, operated in a voltage window of 1.0 ∼ 4.0 V, delivers a high specific energy of 135 Wh kg À 1 at 250 W kg À 1 and a maximum power of 25 kW kg À 1 with the output 69 Wh kg À 1 . Figure 5. Electrochemical performance of SIHCs with different mass ratios between CNS and AC. (a) CV curves, (b) GCD profiles with the mass ratio of 1 : 1, (c) the energy/power densities of SIHCs with mass ratios of 1 : 2, 1 : 1 and 2 : 1, (d) Ragone plots of SIHCs, and (e) cycling stability. Inset of (e) shows the digital picture of a green "SIHC" LED logo powered by obtained hybrid capacitor.

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Carbon Nanosheet Anode for Sodium‐Ion Storage and Its Application in Sodium‐Ion Hybrid Capacitors

et al. 2020

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“…Three-dimensionalc arbon frameworks possess an amorphous and disordered structure, with al arge number of interconnected channels, facilitating ion migration. [134] Liu et al employed garlic as the carbon precursor to synthesize both anode and ChemSusChem 2020ChemSusChem , 13,1275ChemSusChem -1295 www.chemsuschem.org cathodee lectrodes for SICs through different approaches. [135] The HC-based anode, prepared by simple pyrolysis, exhibited a blocklike morphology with as mooth surface and irregular size.…”

Section: Three-dimensional Carbonsmentioning

confidence: 99%

Biomass‐Derived Carbons for Sodium‐Ion Batteries and Sodium‐Ion Capacitors

et al. 2020

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In the past decade, the rapid development of portable electronic devices, electric vehicles, and electrical devices has stimulated extensive interest in fundamental research and the commercialization of electrochemical energy‐storage systems. Biomass‐derived carbon has garnered significant research attention as an efficient, inexpensive, and eco‐friendly active material for energy‐storage systems. Therefore, high‐performance carbonaceous materials, derived from renewable sources, have been utilized as electrode materials in sodium‐ion batteries and sodium‐ion capacitors. Herein, the charge‐storage mechanism and utilization of biomass‐derived carbon for sodium storage in batteries and capacitors are summarized. In particular, the structure–performance relationship of biomass‐derived carbon for sodium storage in the form of batteries and capacitors is discussed. Despite the fact that further research is required to optimize the process and application of biomass‐derived carbon in energy‐storage devices, the current review demonstrates the potential of carbonaceous materials for next‐generation sodium‐related energy‐storage applications.

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“…Therefore, carbon materials with various micro/nanostructures, including microspheres, nanowires, nanotubes, and nanosheets, have been synthesized and used in NICs. By building 3D frameworks, carbon materials will possess interconnected structure and rich channels, which are beneficial to the electronic and ion migration . Yan and co‐workers reported a simple method to prepare 3D framework carbon (3DFC) and 3D framework activated carbon (3DFAC), which have both of the above advantages by the strategy of direct calcination of sodium citrate without any complex procedure .…”

Section: Materials For Sodium‐ion Capacitorsmentioning

confidence: 99%

Advanced Materials for Sodium‐Ion Capacitors with Superior Energy–Power Properties: Progress and Perspectives

Zhang

et al. 2019

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The ORCID identification number(s) for the author(s) of this article can be found under https://doi.org/10. 1002/smll.201902843. Developing electrochemical energy storage devices with high energy-power densities, long cycling life, as well as low cost is of great significance. Sodium-ion capacitors (NICs), with Na + as carriers, are composed of a high capacity battery-type electrode and a high rate capacitive electrode. However, unlike their lithium-ion analogues, the research on NICs is still in its infancy. Rational material designs still need to be developed to meet the increasing requirements for NICs with superior energy-power performance and low cost. In the past few years, various materials have been explored to develop NICs with the merits of superior electrochemical performance, low cost, good stability, and environmental friendliness. Here, the material design strategies for sodium-ion capacitors are summarized, with focus on cathode materials, anode materials, and electrolytes. The challenges and opportunities ahead for the future research on materials for NICs are also proposed. www.advancedsciencenews.com www.small-journal.com to LICs, NICs are still in their infancy stage with many difficulties for their practical application. [23] For example, many battery-type electrode materials for lithium ion storage cannot meet the requirements of NIC devices due to the large size of Na + ions. In addition, due to the redox potential of Na/Na + is 0.3 V higher than that of Li/Li + , the working voltage ranges of NICs are expected to be a little narrower than LICs, which may influence the energy densities of NICs. Moreover, the electrolyte should provide a rapid migration process of Na + ions. Therefore, the rational material design will play crucial roles in the electrochemical performance improvement of NICs.So far, there are few papers which summarize the recent progress in NIC research area. In particular, the materials used in NICs, including anode, cathode, and electrolyte, have not been systematically reviewed. In this article, we focus on the latest advances in the cathode materials, anode materials, and electrolytes for NICs. First, we review the energy storage mechanism and demonstrate the configurations of NICs; then, we summarize the recent progress on electrode materials, including anode materials, cathode materials, as well as different electrolytes for NICs; finally, the challenges and future prospects for NIC research are proposed.

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Three-dimensional carbon framework as a promising anode material for high performance sodium ion storage devices

Cited by 55 publications

References 40 publications

Carbon Nanosheet Anode for Sodium‐Ion Storage and Its Application in Sodium‐Ion Hybrid Capacitors

Carbon Nanosheet Anode for Sodium‐Ion Storage and Its Application in Sodium‐Ion Hybrid Capacitors

Biomass‐Derived Carbons for Sodium‐Ion Batteries and Sodium‐Ion Capacitors

Advanced Materials for Sodium‐Ion Capacitors with Superior Energy–Power Properties: Progress and Perspectives

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