We report on the generation of time-bin entangled photon pairs from a semiconductor quantum dot via pulsed resonant biexciton generation. Based on theoretical modeling we optimized the duration of the excitation pulse to minimize the laser-induced dephasing and increase the biexcitonto-background single exciton occupation probability. This results in a high degree of entanglement with a concurrence of up to 0.78(6) and a 0.88(3) overlap with a maximally entangled state. Theoretical simulations also indicate a power dependent nature of the dephasing during the laser excitation that limits the coherence of the excitation process.Single semiconductor quantum dots, due to their discrete energy structure, constitute an antibunched single photon source at a well defined frequency and with inherently sub-Poissonian statistics [1]. They generate single photons through a recombination of an exciton, a quasi particle formed by a Coulomb-bound electron from the conduction band and a hole from the valence band. In a more refined operation mode employing biexcitons, the Coulomb-bound four-carrier states containing two electrons and two holes, quantum dots can provide pairs of photons emitted in a fast cascade very similar to the original atomic cascade experiment by Aspect et al. [2]. It has been demonstrated that in the absence of the fine structure splitting of the bright exciton levels, such a cascade exhibits polarization entanglement [3][4][5][6][7][8]. Entanglement of photons is a fundamental resource for long distance quantum communications [9,10], where it forms the central part of various quantum communication protocols like teleportation [11] and entanglement swapping [12]. In addition, it is an essential element of linear optical quantum computing [13].The ability to achieve entanglement of photons from a quantum dot is not limited to polarization. Recently, it has been shown that the biexciton-exciton cascade can also be entangled in its emission time (time-bin) [14]. This type of entanglement (encoding) is important for optical-fibre based quantum communication [15] due to the fact that polarization entanglement can suffer from degradation in an optical fibre outside laboratory conditions [16]. In addition, a method to perform linear optical quantum computing with photons entangled in time-bin has been demonstrated recently [17]. Apart from the obvious goal to generate entangled photon pairs, there are further reasons for investigating the time-bin entanglement in photons emerging from a quantum dot. Namely, this method of entanglement calls for a coherent excitation and therefore is an excellent tool for investigating the coherence properties of a quantum dot system. It is precisely resonant excitation (especially two photonresonant excitation of the biexciton [18,19]) combined with a quantum dot system that exhibits a high degree of coherence, that is a sine qua non for optimal use of quantum dot photons in quantum information processing.Here, we report on an unprecedented degree of timebin entanglement from a...