Transfer of the positive charge in non-polar liquids studied by pulse radiolysis

Mehnert, R.; Brede, O.; Bös, J.; Naumann, W.

doi:10.1016/0304-3886(82)90073-0

Cited by 16 publications

(5 citation statements)

References 15 publications

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“…For example, it is well known that a large difference in ionization potentials (∆I = 1.56 eV) results in a maximum rate of charge transfer, which becomes diffusion-controlled (k diff = 2 × 10 11 l mol -1 s -1 ). In particular, this was experimentally found by pulse radiolysis [29,30] in liquid heptane as a solvent, when maximum rates of electron transfer from amines to the radical cations of alkanes were attained at the difference between ionization potentials of ∆I ≈ 1.5 eV:…”

Section: Figmentioning

confidence: 89%

Ion-molecule reactions of primary radical cations in the liquid-phase radiolysis of n-alkanes: An EPR study

Belevskii¹,

Belopushkin²

2005

High Energy Chem

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Section: Figmentioning

confidence: 89%

Ion-molecule reactions of primary radical cations in the liquid-phase radiolysis of n-alkanes: An EPR study

Belevskii¹,

Belopushkin²

2005

High Energy Chem

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“…Highest transfer rates have been observed when the difference of ionization potentials is 41 eV (Mehnert et al, 1982).…”

Section: Generation Of Ions In Non-polar Liquidsmentioning

confidence: 97%

The mobility of positive and negative ions in liquid xenon

Schmidt

Hilt

Illenberger

et al. 2005

Radiation Physics and Chemistry

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“…The reported hole mobility for heptane is 2x10-6m2/Vs [24]. Warman et al [25] give a value of 9.5x10-'m2/Vs for cyclohexane and 9~1 0 -~m~/ V s for trans-decalin.…”

Section: Charge Transportmentioning

confidence: 97%

Basic electrical processes in dielectric liquids

Lewis

1994

IEEE Trans. Dielect. Electr. Insul.

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The basic processes of electrical conduction in dielectric liquids are reviewed, attention being drawn to the similarities between conductive electrolytes and insulating liquids. The concepts of the electronic amorphous solid state are employed to provide a framework for the review. The conditions at metal electrodes can be incorporated naturally into the scheme, and it is known that the space charge layers occurring on them can control conduction. Although electrical breakdown itself is not considered, the underlying electronic processes which will develop when breakdown electrical fields exist in the liquid are considered.

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Transfer of the positive charge in non-polar liquids studied by pulse radiolysis

Cited by 16 publications

References 15 publications

Ion-molecule reactions of primary radical cations in the liquid-phase radiolysis of n-alkanes: An EPR study

Ion-molecule reactions of primary radical cations in the liquid-phase radiolysis of n-alkanes: An EPR study

The mobility of positive and negative ions in liquid xenon

Basic electrical processes in dielectric liquids

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