Ga 9 with a resolution of~0.9 eV. Peak splitting of the YbLg 4 line was observed in all the recorded spectra and was attributed to the two components originating from the LS coupling of the Yb5p hole, the 0 spectra of the mixed valence intermetallics, i.e. YbNi 3 Ga 9 (v = 2.59) and b-YbAlB 4 (v = 2.75), were fairly well reproduced by averaging the spectra of divalent Yb and trivalent YbNi 3 Al 9 , which suggests the possibility of using the YbLg 4 emission for determining the valence of Yb intermetallics. In trivalent Yb compounds, the relative intensity of Lg 4 compared with that of Lg 4 0 , as well as the appearance of a high-energy satellite, was found to be influenced by the ligands around the Yb ions. With the aid of preliminary atomic multiplet and band structure calculations, the differences in the valence band structure and resultant screening effects on the O II,III À1 states were determined to be the possible causes for the observed ligand dependence.