Conventional von Neumann architecture employs a physically distinct processor and memory. This results in considerable delay and energy costs, which is referred to as the von Neumann bottleneck. [1][2][3] Additionally, the memory wall, that is, the performance difference between memory and processing units, is continuously increasing and has become a key concern in the Internet of Things era. Therefore, a novel method of in-memory computing called neuromorphic computing was introduced, which allows concurrent logic and memory operations. [4][5][6] By combining logic and memory functionalities, neuromorphic computing can prevent frequent, time-consuming data transfers and thus significantly reduce power consumption.Neuromorphic computing requires synaptic devices with low-power consumption, multilevel conductance, high switching speeds, and small sizes. [7][8][9][10][11][12][13][14][15][16] In this regard, memristor devices, whose resistance states can be modified using electrical voltages, are promising candidates for synaptic devices, including resistive memristors, [7][8][9][10] magnetic tunnel junctions, [11][12][13] and phase-change memristors. [14][15][16] Recently, ferroelectric tunnel junctions (FTJs) have attracted considerable research attention as candidates for memristor devices in neuromorphic computing. [17][18][19] Under an applied voltage, the polarization of collectively ordered electrical dipoles in ferroelectric materials can be switched, resulting in a change in tunnel electroresistance (TER). Since the discovery of ferroelectricity in HfO 2 -based thin films in 2011, FTJs employing HfO 2 -based ferroelectric materials have piqued the interest of researchers owing to their compatibility with CMOS technologies. [20] In addition, FTJs have advantages of low-power operation, high access speeds, excellent scalability, and good durability. Accordingly, extensive efforts have been directed toward improving the performance of FTJs. The structure of an FTJ has evolved from metal-ferroelectric-metal to metal-ferroelectric-insulator-metal and metal-ferroelectric-insulator-semiconductor (MFIS) stacks as the asymmetric barrier potential profile between the top and bottom electrodes increases the TER ratio. [21,22] Numerous studies have indicated that the remnant polarization in FTJs can be improved by optimizing the fabrication parameters, such as the rapid thermal annealing (RTA) temperature, [23] thickness of the