Triboelectric nanogenerators (TENGs) stand out as an attractive form of technology for the efficient harvest of mechanical energy and the powering of wearable devices due to their light weight, simplicity, high power density, and efficient vibration energy scavenging capabilities. However, the requirement for micro/nanostructures and/or complex and expensive instruments hinders their cheap mass production, thus limiting their practical applications. By using a simple, cost-effective, fast spray-coating process, we develop high-performance UV-curable triboelectric coatings for large-scale energy harvesting. The effect of different formulations and coating compositions on the triboelectric output is investigated to design triboelectric coatings with high output performance. The TENG based on a hybrid coating exhibits high output performance of 54.5 μA current, 1228.9 V voltage, 163.6 nC transferred charge and 3.51 mW output power. Moreover, the hybrid coatings show good long-term output stability. All the results indicate that the designed triboelectric coatings show great potential for large-scale energy harvesting with the advantages of cost-effectiveness, fast fabrication, easy mass production and long-term stability.