TUD-1: synthesis and application of a versatile catalyst, carrier, material…

Abstract

Mesoporous TUD-1 and M-TUD-1 are straightforward to prepare via an environmentally benign synthesis. The resulting materials are excellent catalysts for oxidations, C–C bond forming reactions and photocatalysis. Furthermore the materials have shown potential for the slow release of drugs and as contrast agents.

Preparation, characterization and catalytic performance of HPW-TUD-1 catalyst on oxidative desulfurization

“…TUD-1 material is applied as HPW support due to two reasons. Firstly, TUD-1 materials have tunable pore and high surface area, and can be easily incorporate by metal ion [10][11][12], so we infer TUD-1 material incorporated by HPW can provide the pore volume and surface area needed by ODS catalyst. Secondly, the synthesizing process of TUD-1 material use By incorporating H 3 PW 12 O 40 (HPW) heteropolyacid into mesoporous TUD-1 materials, a series of HPW-TUD-1 catalysts were synthesized.…”

The impact of the copper source on the synthesis of meso-structured CuTUD-1: a promising catalyst for phenol hydroxylation

“…6 In the series of mesoporous materials family, recently 35 added TUD-1 material have been studied as excellent support for various catalytically active species. 7 Though TUD-1 possessed disordered pores, advantages such as easy synthesis, interconnected narrow pore channels, tunable pore size, hydrothermal stability etc., have been succeeding its applications 40 as a heterogeneous catalyst. 7 Copper salts or copper complexes have been employed as an active catalyst for oxidative transformation of organic compounds.…”

“…7 Though TUD-1 possessed disordered pores, advantages such as easy synthesis, interconnected narrow pore channels, tunable pore size, hydrothermal stability etc., have been succeeding its applications 40 as a heterogeneous catalyst. 7 Copper salts or copper complexes have been employed as an active catalyst for oxidative transformation of organic compounds. 8 Heterogenizing such active catalytic sites by various methods have been explored.…”

Decomposition of cyclohexyl hydroperoxide over bimetallic mesoporous materials containing cobalt and chromium

“…Its main advantage is the excellent framework for incorporation of different metals as isolated metals rather than metal oxide clusters. With this advantage, a wide range of M‐TUD‐1 with framework‐incorporated metals can be prepared . A noteworthy development in this regard is the result by Anand with redox metals Ti, Fe, Co, and Cr incorporated in the framework of TUD‐1.…”