Two new layered complexes supported by helical <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si1.gif" overflow="scroll"><mml:mrow><mml:mo stretchy="false">{</mml:mo><mml:msub><mml:mrow><mml:mtext>VO</mml:mtext></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub><mml:msubsup><mml:mrow><mml:mo stretchy="false">}</mml:mo></mml:mrow><mml:mrow><mml:mi>n</mml:mi></mml:mrow><mml:mrow><mml:mi>n</mml:mi><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math> chains: Hydrotherma

The new metavanadate [Cu(H 2 O)(C 5 H 14 N 2 ) 2 ][VO 3 ] 2 (C 5 H 14 N 2 is 2,2-dimethylpropyldiamine) (1) was synthesized under solvothermal conditions. The compound crystallizes in the rhombohedral space group R3m with a ϭ 28.6984 (15), c ϭ 6.4309 (3), V ϭ 4586.9(4) Å 3 , Z ϭ 9. The main structural motifs are helical metavanadate {VO 3 } n nϪ chains made by corner-sharing [VO 4 ] 3Ϫ tetrahedra and [Cu(H 2 O)(C 5 H 14 N 2 ) 2 ] 2ϩ complexes with the Cu 2ϩ ion being in a distorted square-pyramidal coordination environment. The complexes are located between left-and right-

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[Cu(H₂O)(C₅H₁₄N₂)₂][VO₃]₂ – A Metavanadate Containing Right‐ and Left‐Handed Helical Chains

Wutkowski

Näther

Bensch

2009

Zeitschrift anorg allge chemie

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Cerium tartrate as a corrosion inhibitor for AA 2024-T3

Shi

Wei

et al. 2015

Corrosion Science

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Two complexes isolated from solutions under solvothermal conditions: [CuCl2(C5H14N2)2]·4 H2O with the copper complex enwrapped in a unique self-assembled water layer of fused H2O decamers and [Co(CO3)(C5H14N2)2]Cl·H2O with the cobalt complex fixed in an extended hydrogen bond network

Wutkowski

Näther

Bensch

2011

Inorganica Chimica Acta

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Two new layered complexes supported by helical {VO3}nn- chains: Hydrotherma

Cited by 10 publications

References 29 publications

[Cu(H₂O)(C₅H₁₄N₂)₂][VO₃]₂ – A Metavanadate Containing Right‐ and Left‐Handed Helical Chains

[Cu(H₂O)(C₅H₁₄N₂)₂][VO₃]₂ – A Metavanadate Containing Right‐ and Left‐Handed Helical Chains

Cerium tartrate as a corrosion inhibitor for AA 2024-T3

Two complexes isolated from solutions under solvothermal conditions: [CuCl2(C5H14N2)2]·4 H2O with the copper complex enwrapped in a unique self-assembled water layer of fused H2O decamers and [Co(CO3)(C5H14N2)2]Cl·H2O with the cobalt complex fixed in an extended hydrogen bond network

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Two new layered complexes supported by helical {VO3}nn- chains: Hydrotherma

Cited by 10 publications

References 29 publications

[Cu(H2O)(C5H14N2)2][VO3]2 – A Metavanadate Containing Right‐ and Left‐Handed Helical Chains

[Cu(H2O)(C5H14N2)2][VO3]2 – A Metavanadate Containing Right‐ and Left‐Handed Helical Chains

Cerium tartrate as a corrosion inhibitor for AA 2024-T3

Two complexes isolated from solutions under solvothermal conditions: [CuCl2(C5H14N2)2]·4 H2O with the copper complex enwrapped in a unique self-assembled water layer of fused H2O decamers and [Co(CO3)(C5H14N2)2]Cl·H2O with the cobalt complex fixed in an extended hydrogen bond network

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[Cu(H₂O)(C₅H₁₄N₂)₂][VO₃]₂ – A Metavanadate Containing Right‐ and Left‐Handed Helical Chains

[Cu(H₂O)(C₅H₁₄N₂)₂][VO₃]₂ – A Metavanadate Containing Right‐ and Left‐Handed Helical Chains