2015
DOI: 10.1177/1934578x1501000624
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Two Novel Spirostene Glycosides from Selaginella chrysocaulos and their Chemotaxonomic Significance

Abstract: During an investigation of the Indian heterosporous fern Selaginella chrysocaulos, two novel C 28 spirostene monosides, chrysocauloside A and B were identified. Chrysocauloside A (1,3-dihydroxy-20S,22R-spirost-5-ene-1-yl -D-glucopyranoside) and chrysocauloside B (1,3-dihydroxy-20S,22R-spirost-5-ene-1-yl -D-galactopyranoside) are O-glycosylated at C-1 and each bear a methyl group at C-24 and C-25. Spectroscopic (NMR) and MS data for the new compounds are given and the taxonomic significance of the occurre… Show more

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Cited by 4 publications
(3 citation statements)
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“…Additionally, the first abietane diterpenoid from the genus Selaginella (isolated from S. involven Spring) was reported in 2014 (Long et al 2014). Two novel C-28 spirostene monosides, chrysocauloside A (1β,3β-dihydroxy-20S,22R-spirost-5-ene-1-yl-β-D-glucopyranoside) and chrysocauloside B (1β,3β-dihydroxy-20S,22R-spirost-5-ene-1-yl-β-D-galactopyranoside), were identified from S. ehrysocaulos; both compounds are O-glycosylated at C-1 and bear a methyl group at C-24 and C-25 (Kunert et al 2015).…”
Section: Othersmentioning
confidence: 99%
“…Additionally, the first abietane diterpenoid from the genus Selaginella (isolated from S. involven Spring) was reported in 2014 (Long et al 2014). Two novel C-28 spirostene monosides, chrysocauloside A (1β,3β-dihydroxy-20S,22R-spirost-5-ene-1-yl-β-D-glucopyranoside) and chrysocauloside B (1β,3β-dihydroxy-20S,22R-spirost-5-ene-1-yl-β-D-galactopyranoside), were identified from S. ehrysocaulos; both compounds are O-glycosylated at C-1 and bear a methyl group at C-24 and C-25 (Kunert et al 2015).…”
Section: Othersmentioning
confidence: 99%
“…Selaginella research exhaustively needs to be conducted to explore all natural products constituents and their bioactivities. According to Kunert, et al, (2015) the genus is especially well-known to be a rich source of biflavonoids, some of which have reported pharmacological activities. Selaginella species have attracted attention of researchers worldwide due to the presence of high value bioactive molecules such as flavonoid, biflavonoids, tannin, saponin, triterpene, steroid and many other secondary metabolites.…”
Section: Molecular Bioactivitiesmentioning
confidence: 99%
“…The genus Selaginella ( Selaginellaceae ) is composed of approximately 70 species, many of which are distributed in China where many have been used for treating bleeding, jaundice, gonorrhea, and idiopathic thrombocytopenic purpura in traditional Chinese medicine. 1 The genus is known as a rich source of secondary metabolites including flavonoids, 2 selaginellin, 3 alkaloids, 4 lignans, 5 and steroids, 6 which have been reported to exhibit diverse pharmacological activities, such as antitumor, 7,8 antibiosis, 9,10 antiviral, 11 and antioxidant. 12 S. trichoclada Alsto, commonly known as “boyundan, yanbaicao and tubozi” in folk medicine, is mainly distributed in the southern area of China, where it is used widely as a herbal medicine for clearing heat and promoting diuresis and relieving cough.…”
mentioning
confidence: 99%