Although multicomponent inorganic thin films (metal-oxides,
-carbides,
-nitrides, and -chalcogenides) have been synthesized by polymer-assisted
deposition (PAD), synthesis of high-performance transparent conducting
oxides (TCOs) has been rarely reported. TCO requires (i) removal of
impurities, (ii) high-density oxide film, (iii) homogeneity in crystal
structures and film morphology, and (iv) controllable elemental doping.
This study performs a systematic investigation on preparation of stable
multicomponent metal–polymer complex solutions by removing
the counteranions in the solution. This study also proposes accurate
acid–base titration for each metal species in order to minimize
the amount of PEI, thus maximizing the density of the film. As a representative
TCO, Sn-doped In2O3 (ITO) films have been achieved.
The ITO film has an excellent sheet resistance (24.5 Ω/sq) at
93% optical transparency, with a figure of merit of 2.1 × 10–2 Ω–1, which is comparable
to the best.