Über die Anlagerung von Diacyl‐methanen an Verbindungen vom Typ des Isopropyliden‐malonesters

Scheiber, Johannes; Meisel, Fritz

doi:10.1002/cber.19150480139

Cited by 25 publications

(4 citation statements)

References 11 publications

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“…For example, by 1919, more than 60 publications had appeared in which ozonolysis had been applied to structure problems, including such (then) esoteric subjects as the structures of enols [38]. Semmler alone [39] had reported the use of O 3 in at least 18 papers on his investigations of terpene structures.…”

Section: Reaction Of O 3 With Organicmentioning

confidence: 99%

The History of Ozone. Part III

Rubin

2003

Helvetica Chimica Acta

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The introduction of ozone into organic chemistry is due to the work of C. D. Harries, first in Berlin but mainly in Kiel, during the period 1903–1916. He established experimental procedures for ozonolysis, demonstrated the generality of the reaction of unsaturated compounds with ozone, and showed that ozone could be used for the synthesis of a variety of sensitive compounds. Most important for the future development of organic chemistry, he established that ozonolysis could be an important tool for determining the structures of organic compounds. He also initiated investigations into the mechanism of ozone reactions with alkenes, which culminated about forty years later in the Criegee mechanism for ozonolysis.

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Section: Reaction Of O 3 With Organicmentioning

confidence: 99%

The History of Ozone. Part III

Rubin

2003

Helvetica Chimica Acta

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“…The majority of carbocyclic compounds obtained from mesityl oxide are six-membered and the formation of a number of these materials serve as excellent examples of several condensation types. Type 4 condensation is illustrated by the sodium-catalyzed reaction of ethyl or methyl cyanoacetate with mesityl oxide (133), yielding a mixture of the open-chain adduct LVI and the cyclohexadione LVII. LVI, when separated, is readily cyclized to LVII, establishing the probable mechanism.…”

Section: Cyclohexane Derivativesmentioning

confidence: 99%