1910
DOI: 10.1002/cber.191004301152
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Über die Löslichkeit von Gasen in Metallen und Legierungen

Abstract: nu5 p -Chloraniliu iind Benzoylchlorid, wurde mittels Phosphorpentachlorid in das Imidchlorid ') verwnndelt. Durch Cyankalium v i r d dnsselbe fast ohne jede Nebenreaktion in das P h e n 3 . 1 -r -c y a n -a z o m e t h i n -p -c h l o r p h e n p l , CCRS .C(CN):N .(;6Hc .C1, iibergefuhrt. Dasselbe ist liislich in Alkohol, -4ther, Henzol und PetrolCther, unloslich in Wasser. Beim Umkrystallisieren aus Alkohol wird es in schoaen, gelben, langen Nadeln erhalten, die bei 94O sclimelzen. 0.1487 y Sbbt.: 0.3303 g … Show more

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Cited by 148 publications
(24 citation statements)
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“…with n = 0.5 (Sieverts and Krumbhaar, 1910). Here, N m is the transmembrane flux, defined at the radial coordinate of the palladium layer (r m ), Q(T) is the temperature-dependent permeance, p H 2 ,r and p H 2 ,p are the retentate-side and permeate-side H 2 partial pressures, respectively.…”
Section: Palladiummentioning
confidence: 99%
“…with n = 0.5 (Sieverts and Krumbhaar, 1910). Here, N m is the transmembrane flux, defined at the radial coordinate of the palladium layer (r m ), Q(T) is the temperature-dependent permeance, p H 2 ,r and p H 2 ,p are the retentate-side and permeate-side H 2 partial pressures, respectively.…”
Section: Palladiummentioning
confidence: 99%
“…The simultaneous changes in solubility and diffusivity lead to a value of permeability ~1.7 times higher for alloys with 23 wt% of Ag than for pure Pd at 350°C [15,16]. Different measurement principles can be applied to determine hydrogen solubility in palladium and its alloys [17], of which volumetric [18][19][20] and gravimetric [21][22][23] absorption, sample dilation measurements [24] and electrical resistance measurements [25] are a few examples. Flanagan and Oates [26] reported a series of methods used to estimate diffusivity in the palladium-hydrogen system.…”
Section: Introductionmentioning
confidence: 99%
“…According to Sieverts' law, [2] the is not clear. Despite this lack of understanding, it is believed hydrogen concentration in lattice sites C L depends on the that trapping plays an important role in hydrogen embrittlepressure p H 2 of the hydrogen molecules in the void: ment.…”
mentioning
confidence: 98%