1963
DOI: 10.1002/macp.1963.020690112
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Über die polymerisation von methacrylsäuremethylester durch merkaptane in gegenwart von chlorid1. XII. Mitt. polymerisationen und polymerisationskatalysatoren2

Abstract: ZUSAMMENFASSUNG:Die Polymerisation von Methacrylsauremethylester durch p-Thiokresol oder 1-bzw. 8-Merkaptohexan in Gegenwart von Chlorid erfolgt nach einer kurzen Induktionsperiode unter Bildung von Makromolekiilen, die jeweils zwei Schwefel-Atome enthalten. Der Mechanismus der Polymerisationsauslosung wird diskutiert. SUMMARY:The polymerization of methyl methacrylate by thiocresol, or 1-or 2-mercaptohexane in presence of chloride occurs after a short induction period with formation of macromolecules which con… Show more

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Cited by 7 publications
(1 citation statement)
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“…More recently, N,N ‐dihydroxyethyl‐ p ‐toluidine (DEPT), which is more reactive and discolors the resin less than DMPT, have used instead of DMPT. On the other hand, to generate free radical for initiating polymerization, a reaction between 1,3,5‐trimethylbarbituric acid (TMBA) and copper‐ion or chloride‐ion has been applied 1–30. Thus, TMBA generates highly concentrated free radical and accelerates polymerization 31–40…”
Section: Introductionmentioning
confidence: 99%
“…More recently, N,N ‐dihydroxyethyl‐ p ‐toluidine (DEPT), which is more reactive and discolors the resin less than DMPT, have used instead of DMPT. On the other hand, to generate free radical for initiating polymerization, a reaction between 1,3,5‐trimethylbarbituric acid (TMBA) and copper‐ion or chloride‐ion has been applied 1–30. Thus, TMBA generates highly concentrated free radical and accelerates polymerization 31–40…”
Section: Introductionmentioning
confidence: 99%