Über katalytische Wirkungen kolloidaler Metalle der Platingruppe. VI. Reduktionskatalysen mit kolloidalem Palladium

Paal, C.; Gerum, J.

doi:10.1002/cber.19090420222

Cited by 14 publications

(1 citation statement)

References 7 publications

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“…The first example of nitrile hydrogenation was published by Sabatier in 1905 with a reduced Ni catalyst that performed the unselective reduction of nitriles with H 2 to primary, secondary, and tertiary amines [503]. While numerous catalytic systems have been developed such as colloidal Pd [504], Ni Raney [505], Pt oxide [506], Raney Co [507], Cu 2 Cr 2 O 5 [508], supported platinum group metals metals [509], metal borides [510], metal alloys [511], the less active Raney nickel and copper chromite are still used industrially due to their lower price. However, their problematic toxicity promoted the development of non-noble transition metals Ni [512], Co [513], Cu [514], and Fe [515] heterogeneous catalysts.…”

Section: Hydrogenationmentioning

confidence: 99%

Literature review: state-of-the-art hydrogen storage technologies and Liquid Organic Hydrogen Carrier (LOHC) development

D’Ambra,

Gébel

2023

Sci. Tech. Energ. Transition

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Greenhouse gas anthropogenic emissions have triggered global warming with increasingly alarming consequences, motivating the development of carbon-free energy systems. Hydrogen is proposed as an environmentally benign energy vector to implement this strategy, but safe and efficient large-scale hydrogen storage technologies are still lacking to develop a competitive Hydrogen economy. LOHC (Liquid Organic Hydrogen Carrier) improves the storage and handling of hydrogen by covalently binding it to a liquid organic framework through catalytic exothermic hydrogenation and endothermic dehydrogenation reactions. LOHCs are oil-like materials that are compatible with the current oil and gas infrastructures. Nevertheless, their high dehydrogenation enthalpy, platinoid-based catalysts, and thermal stability are bottlenecks to the emergence of this technology. In this review, hydrogen storage technologies and in particular LOHC are presented. Moreover, potential reactivities to design innovative LOHC are discussed.

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Section: Hydrogenationmentioning

confidence: 99%

Literature review: state-of-the-art hydrogen storage technologies and Liquid Organic Hydrogen Carrier (LOHC) development

D’Ambra,

Gébel

2023

Sci. Tech. Energ. Transition

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Amines By Reduction

Natte

Jagadeesh

2021

Kirk-Othmer Encyclopedia of Chemical Technology

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Among different kinds of chemicals, amines represent essential compounds widely used as fine and bulk chemicals, which serve as key intermediates and central precursors in chemical, pharmaceuticals, agrochemical, and materials industries. Moreover, amine functionalities constitute important motifs presented in a large of number of life science molecules, which play vital roles in their activities and functions. For the synthesis of amines, catalytic reduction of nitro compounds and nitriles and reductive aminations are widely used to produce primary, secondary, and tertiary amines as well as drug targets. In this article, we discuss the recent developments on reduction of nitro compounds, nitriles, and reductive aminations using mainly nonnoble metal‐based catalysts in the presence of molecular hydrogen to access different kinds of amines.

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Wissenschaftliche Übersichten

Lottermoser

1913

Zeitschrift für Elektrochemie und angewandte physikalische Chem

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Über katalytische Wirkungen kolloidaler Metalle der Platingruppe. VI. Reduktionskatalysen mit kolloidalem Palladium

Cited by 14 publications

References 7 publications

Literature review: state-of-the-art hydrogen storage technologies and Liquid Organic Hydrogen Carrier (LOHC) development

Literature review: state-of-the-art hydrogen storage technologies and Liquid Organic Hydrogen Carrier (LOHC) development

Amines By Reduction

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